Corrosion behavior of Zn-TiO2 and Zn-ZnO electrodeposited coatings in 3.5% NaCl solution

Electrodeposition is a widely used method to protect metallic materials from corrosion. Electrodeposited coatings provide the metal substrate with both cathodic protection and a barrier effect. The corrosion resistance achieved with this type of zinc-electroplating process in increased by adding nan...

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Autores principales: Cabral Miramontes, José Ángel, Bastidas, David M., Baltazar, M.A, Zambrano Robledo, Patricia del Carmen, Bastidas, José María, Almeraya Calderón, Facundo, Gaona Tiburcio, Citlalli
Formato: Artículo
Lenguaje:inglés
Publicado: Electrochemical Science Group 2019
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Acceso en línea:http://eprints.uanl.mx/25058/1/46.pdf
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author Cabral Miramontes, José Ángel
Bastidas, David M.
Baltazar, M.A
Zambrano Robledo, Patricia del Carmen
Bastidas, José María
Almeraya Calderón, Facundo
Gaona Tiburcio, Citlalli
author_facet Cabral Miramontes, José Ángel
Bastidas, David M.
Baltazar, M.A
Zambrano Robledo, Patricia del Carmen
Bastidas, José María
Almeraya Calderón, Facundo
Gaona Tiburcio, Citlalli
author_sort Cabral Miramontes, José Ángel
collection Repositorio Institucional
description Electrodeposition is a widely used method to protect metallic materials from corrosion. Electrodeposited coatings provide the metal substrate with both cathodic protection and a barrier effect. The corrosion resistance achieved with this type of zinc-electroplating process in increased by adding nanometric materials to the electrolytic bath. In the present research, coatings were obtained by electrodeposition of pure zinc, Zn-TiO2 and Zn-ZnO nanoparticles. The coatings were generated by immersion in a chloride acid bath applying a current density of 0.05 and 0.10 A/cm2 for 1 min and adding 2 g/l of TiO2 or ZnO nanoparticles. Corrosion behaviour was evaluated with potentiodynamic polarization curves and the electrochemical impedance spectroscopy (EIS) technique using a 3.5% NaCl test solution. After electrochemical testing, the coating surface morphology was analysed by scanning electron microscopy (SEM) and the atomic composition by energy dispersive X-ray spectroscopy (EDS). The electrodeposited coating thickness was measured using the ultrasound technique. The coating thickness was less than 2.5 μm and its corrosion resistance increased with the addition of nanoparticles.
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spelling eprints-250582024-02-22T17:03:14Z http://eprints.uanl.mx/25058/ Corrosion behavior of Zn-TiO2 and Zn-ZnO electrodeposited coatings in 3.5% NaCl solution Cabral Miramontes, José Ángel Bastidas, David M. Baltazar, M.A Zambrano Robledo, Patricia del Carmen Bastidas, José María Almeraya Calderón, Facundo Gaona Tiburcio, Citlalli TA Ingeniería General y Civil Electrodeposition is a widely used method to protect metallic materials from corrosion. Electrodeposited coatings provide the metal substrate with both cathodic protection and a barrier effect. The corrosion resistance achieved with this type of zinc-electroplating process in increased by adding nanometric materials to the electrolytic bath. In the present research, coatings were obtained by electrodeposition of pure zinc, Zn-TiO2 and Zn-ZnO nanoparticles. The coatings were generated by immersion in a chloride acid bath applying a current density of 0.05 and 0.10 A/cm2 for 1 min and adding 2 g/l of TiO2 or ZnO nanoparticles. Corrosion behaviour was evaluated with potentiodynamic polarization curves and the electrochemical impedance spectroscopy (EIS) technique using a 3.5% NaCl test solution. After electrochemical testing, the coating surface morphology was analysed by scanning electron microscopy (SEM) and the atomic composition by energy dispersive X-ray spectroscopy (EDS). The electrodeposited coating thickness was measured using the ultrasound technique. The coating thickness was less than 2.5 μm and its corrosion resistance increased with the addition of nanoparticles. Electrochemical Science Group 2019-04 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/25058/1/46.pdf http://eprints.uanl.mx/25058/1.haspreviewThumbnailVersion/46.pdf Cabral Miramontes, José Ángel y Bastidas, David M. y Baltazar, M.A y Zambrano Robledo, Patricia del Carmen y Bastidas, José María y Almeraya Calderón, Facundo y Gaona Tiburcio, Citlalli (2019) Corrosion behavior of Zn-TiO2 and Zn-ZnO electrodeposited coatings in 3.5% NaCl solution. International Journal of Electrochemical Science, 14. pp. 4226-4239. ISSN 14523981 http://www.electrochemsci.org/ https://doi: 10.20964/2019.05.10
spellingShingle TA Ingeniería General y Civil
Cabral Miramontes, José Ángel
Bastidas, David M.
Baltazar, M.A
Zambrano Robledo, Patricia del Carmen
Bastidas, José María
Almeraya Calderón, Facundo
Gaona Tiburcio, Citlalli
Corrosion behavior of Zn-TiO2 and Zn-ZnO electrodeposited coatings in 3.5% NaCl solution
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Corrosion behavior of Zn-TiO2 and Zn-ZnO electrodeposited coatings in 3.5% NaCl solution
title_full Corrosion behavior of Zn-TiO2 and Zn-ZnO electrodeposited coatings in 3.5% NaCl solution
title_fullStr Corrosion behavior of Zn-TiO2 and Zn-ZnO electrodeposited coatings in 3.5% NaCl solution
title_full_unstemmed Corrosion behavior of Zn-TiO2 and Zn-ZnO electrodeposited coatings in 3.5% NaCl solution
title_short Corrosion behavior of Zn-TiO2 and Zn-ZnO electrodeposited coatings in 3.5% NaCl solution
title_sort corrosion behavior of zn tio2 and zn zno electrodeposited coatings in 3 5 nacl solution
topic TA Ingeniería General y Civil
url http://eprints.uanl.mx/25058/1/46.pdf
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