Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-OL
The asymmetric unit 01 the title compound C"H"N,O" centains one molecule 01 the cempound (L3) (1 ,3-bis(2-nitrobenzylideneamino)propan-2-o1). The molecule shows a chiral e atom but the absolute structure was not possible lo be detemnined by X-ray diffraction. The molecule shows interm...
| Autores principales: | , , , , |
|---|---|
| Formato: | Artículo |
| Lenguaje: | inglés |
| Publicado: |
2010
|
| Materias: | |
| Acceso en línea: | http://eprints.uanl.mx/2110/1/Art2.pdf |
| _version_ | 1824368152244387840 |
|---|---|
| author | Elizondo Martínez, Perla Pérez Rodríguez, Nancy Rodríguez de Barbarín, Cecilia López Cortina, Susana Rodríguez de Luna, Sara Luisa |
| author_facet | Elizondo Martínez, Perla Pérez Rodríguez, Nancy Rodríguez de Barbarín, Cecilia López Cortina, Susana Rodríguez de Luna, Sara Luisa |
| author_sort | Elizondo Martínez, Perla |
| collection | Repositorio Institucional |
| description | The asymmetric unit 01 the title compound C"H"N,O" centains one molecule 01 the cempound (L3) (1 ,3-bis(2-nitrobenzylideneamino)propan-2-o1). The molecule shows a chiral e atom but the absolute structure was not possible lo be detemnined by X-ray diffraction. The molecule shows intermolecular hydrogen bonding involving !he hydroxy group and an imine nitrogen atom of a symmetry related molecule. The molecular distribution shows weak interactions belween oxygen aloms ofthe nitro groups and Iwo different C-H groups 01 benzene rings. The extended weak H bond lomnation, using the NO, groups, probably gives a more stable crystal structure. The molecule represents a precursor of a polyaza macrocylic ligands. |
| format | Article |
| id | eprints-2110 |
| institution | UANL |
| language | English |
| publishDate | 2010 |
| record_format | eprints |
| spelling | eprints-21102019-06-25T08:25:45Z http://eprints.uanl.mx/2110/ Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-OL Elizondo Martínez, Perla Pérez Rodríguez, Nancy Rodríguez de Barbarín, Cecilia López Cortina, Susana Rodríguez de Luna, Sara Luisa Q Ciencias en General QD Química The asymmetric unit 01 the title compound C"H"N,O" centains one molecule 01 the cempound (L3) (1 ,3-bis(2-nitrobenzylideneamino)propan-2-o1). The molecule shows a chiral e atom but the absolute structure was not possible lo be detemnined by X-ray diffraction. The molecule shows intermolecular hydrogen bonding involving !he hydroxy group and an imine nitrogen atom of a symmetry related molecule. The molecular distribution shows weak interactions belween oxygen aloms ofthe nitro groups and Iwo different C-H groups 01 benzene rings. The extended weak H bond lomnation, using the NO, groups, probably gives a more stable crystal structure. The molecule represents a precursor of a polyaza macrocylic ligands. 2010 Article PeerReviewed application/pdf en http://eprints.uanl.mx/2110/1/Art2.pdf http://eprints.uanl.mx/2110/1.haspreviewThumbnailVersion/Art2.pdf Elizondo Martínez, Perla y Pérez Rodríguez, Nancy y Rodríguez de Barbarín, Cecilia y López Cortina, Susana y Rodríguez de Luna, Sara Luisa (2010) Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-OL. Química Hoy, 1 (1). |
| spellingShingle | Q Ciencias en General QD Química Elizondo Martínez, Perla Pérez Rodríguez, Nancy Rodríguez de Barbarín, Cecilia López Cortina, Susana Rodríguez de Luna, Sara Luisa Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-OL |
| thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
| title | Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-OL |
| title_full | Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-OL |
| title_fullStr | Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-OL |
| title_full_unstemmed | Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-OL |
| title_short | Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-OL |
| title_sort | synthesis and crystal structures of a poliaza receptor macroligand 1 3 bis 2 nitrobenzylideneamino propan 2 ol |
| topic | Q Ciencias en General QD Química |
| url | http://eprints.uanl.mx/2110/1/Art2.pdf |
| work_keys_str_mv | AT elizondomartinezperla synthesisandcrystalstructuresofapoliazareceptormacroligand13bis2nitrobenzylideneaminopropan2ol AT perezrodrigueznancy synthesisandcrystalstructuresofapoliazareceptormacroligand13bis2nitrobenzylideneaminopropan2ol AT rodriguezdebarbarincecilia synthesisandcrystalstructuresofapoliazareceptormacroligand13bis2nitrobenzylideneaminopropan2ol AT lopezcortinasusana synthesisandcrystalstructuresofapoliazareceptormacroligand13bis2nitrobenzylideneaminopropan2ol AT rodriguezdelunasaraluisa synthesisandcrystalstructuresofapoliazareceptormacroligand13bis2nitrobenzylideneaminopropan2ol |