Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-OL

The asymmetric unit 01 the title compound C"H"N,O" centains one molecule 01 the cempound (L3) (1 ,3-bis(2-nitrobenzylideneamino)propan-2-o1). The molecule shows a chiral e atom but the absolute structure was not possible lo be detemnined by X-ray diffraction. The molecule shows interm...

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Detalles Bibliográficos
Autores principales: Elizondo Martínez, Perla, Pérez Rodríguez, Nancy, Rodríguez de Barbarín, Cecilia, López Cortina, Susana, Rodríguez de Luna, Sara Luisa
Formato: Artículo
Lenguaje:inglés
Publicado: 2010
Materias:
Acceso en línea:http://eprints.uanl.mx/2110/1/Art2.pdf
Descripción
Sumario:The asymmetric unit 01 the title compound C"H"N,O" centains one molecule 01 the cempound (L3) (1 ,3-bis(2-nitrobenzylideneamino)propan-2-o1). The molecule shows a chiral e atom but the absolute structure was not possible lo be detemnined by X-ray diffraction. The molecule shows intermolecular hydrogen bonding involving !he hydroxy group and an imine nitrogen atom of a symmetry related molecule. The molecular distribution shows weak interactions belween oxygen aloms ofthe nitro groups and Iwo different C-H groups 01 benzene rings. The extended weak H bond lomnation, using the NO, groups, probably gives a more stable crystal structure. The molecule represents a precursor of a polyaza macrocylic ligands.