Transformation Temperatures and Electrochemical behavior of Polycrystalline Fe-Doped Ni-Mn-Ga and Co-Ni-Ga Alloys

The effect of Fe addition on martensitic transformation temperatures and electrochemical behavior was studied in polycrystalline Ni51.4Mn24.8-XGa23.8FeX alloys (1˂x˂2.2) and Co38.3Ni32.1Ga29.6 as alternative to Ni-Mn-Ga alloys which are used as ferromagnetic shape memory alloys. The analysis of corr...

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Autor principal: Sanchez Carrillo, M.
Formato: Artículo
Lenguaje:inglés
Publicado: 2018
Acceso en línea:http://eprints.uanl.mx/16189/1/106.pdf
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author Sanchez Carrillo, M.
author_facet Sanchez Carrillo, M.
author_sort Sanchez Carrillo, M.
collection Repositorio Institucional
description The effect of Fe addition on martensitic transformation temperatures and electrochemical behavior was studied in polycrystalline Ni51.4Mn24.8-XGa23.8FeX alloys (1˂x˂2.2) and Co38.3Ni32.1Ga29.6 as alternative to Ni-Mn-Ga alloys which are used as ferromagnetic shape memory alloys. The analysis of corrosion rates was conducted by cyclic polarization curves with potentiostat-galvanostat equipment. The corrosion morphologies were also analyzed by scanning electron microscopy (SEM). The kinetics of corrosion was found to decrease with increasing Fe content in the alloy, while the martensitic transformation temperatures increased with increasing Fe content. The Co38.3Ni32.1Ga29.6 alloy shows icorr lower than the Ni-Mn-Ga alloy. From results, the studied alloys exhibited a general dissolution in the anodic branch where a spontaneous passive zone occurred at certain potential and some elements like Co, Mn and also Ni were present in a higher percentage in corrosion deposits.
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spelling eprints-161892020-06-09T20:52:47Z http://eprints.uanl.mx/16189/ Transformation Temperatures and Electrochemical behavior of Polycrystalline Fe-Doped Ni-Mn-Ga and Co-Ni-Ga Alloys Sanchez Carrillo, M. The effect of Fe addition on martensitic transformation temperatures and electrochemical behavior was studied in polycrystalline Ni51.4Mn24.8-XGa23.8FeX alloys (1˂x˂2.2) and Co38.3Ni32.1Ga29.6 as alternative to Ni-Mn-Ga alloys which are used as ferromagnetic shape memory alloys. The analysis of corrosion rates was conducted by cyclic polarization curves with potentiostat-galvanostat equipment. The corrosion morphologies were also analyzed by scanning electron microscopy (SEM). The kinetics of corrosion was found to decrease with increasing Fe content in the alloy, while the martensitic transformation temperatures increased with increasing Fe content. The Co38.3Ni32.1Ga29.6 alloy shows icorr lower than the Ni-Mn-Ga alloy. From results, the studied alloys exhibited a general dissolution in the anodic branch where a spontaneous passive zone occurred at certain potential and some elements like Co, Mn and also Ni were present in a higher percentage in corrosion deposits. 2018-06-05 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/16189/1/106.pdf http://eprints.uanl.mx/16189/1.haspreviewThumbnailVersion/106.pdf Sanchez Carrillo, M. (2018) Transformation Temperatures and Electrochemical behavior of Polycrystalline Fe-Doped Ni-Mn-Ga and Co-Ni-Ga Alloys. International Journal of Electrochemical Science. pp. 6666-6675. ISSN 14523981 http://doi.org/10.20964/2018.07.08 doi:10.20964/2018.07.08
spellingShingle Sanchez Carrillo, M.
Transformation Temperatures and Electrochemical behavior of Polycrystalline Fe-Doped Ni-Mn-Ga and Co-Ni-Ga Alloys
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Transformation Temperatures and Electrochemical behavior of Polycrystalline Fe-Doped Ni-Mn-Ga and Co-Ni-Ga Alloys
title_full Transformation Temperatures and Electrochemical behavior of Polycrystalline Fe-Doped Ni-Mn-Ga and Co-Ni-Ga Alloys
title_fullStr Transformation Temperatures and Electrochemical behavior of Polycrystalline Fe-Doped Ni-Mn-Ga and Co-Ni-Ga Alloys
title_full_unstemmed Transformation Temperatures and Electrochemical behavior of Polycrystalline Fe-Doped Ni-Mn-Ga and Co-Ni-Ga Alloys
title_short Transformation Temperatures and Electrochemical behavior of Polycrystalline Fe-Doped Ni-Mn-Ga and Co-Ni-Ga Alloys
title_sort transformation temperatures and electrochemical behavior of polycrystalline fe doped ni mn ga and co ni ga alloys
url http://eprints.uanl.mx/16189/1/106.pdf
work_keys_str_mv AT sanchezcarrillom transformationtemperaturesandelectrochemicalbehaviorofpolycrystallinefedopednimngaandconigaalloys