Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4 − ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding.
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
2012
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| Online Access: | http://eprints.uanl.mx/14933/1/598.pdf |
| Summary: | Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4 − ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding. |
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