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"One pot" microwave assisted synthesis of 5,10,15-tri(4-methoxyphenyl)-20-(4-chlorophentyl)-21H,23H-porphyrin and its zinc (II) complex

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The synthesis of new unsymmetrical A3B porphyrin, 5,10,15-tri(4-methoxyphenyl)-20-(4-chlorophentyl)-21H,23H-porphyrin, 1, and its zinc(II) complex, 5,10,15-tri(4-methoxyphenyl)-20-(4-chlorophentyl)-21,23-Zinc(II)-porphine, 2, was accomplished using both conventional and "one pot" solventle...

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Bibliographic Details
Main Authors: Loredo Calderón, Erika Lilián, Martínez Lejia, Carolina, López Cortina, Susana, Muñoz Flores, Blanca M., Hernández Fernández, Eugenio, Jiménez Pérez, Víctor Manuel, Cuevas Yañez, Erick
Format: Article
Language:English
Published: Universidad Autónoma de Nuevo León 2012
Subjects:
QD Química
Online Access:http://eprints.uanl.mx/13481/1/Art2.pdf
Description
Summary:The synthesis of new unsymmetrical A3B porphyrin, 5,10,15-tri(4-methoxyphenyl)-20-(4-chlorophentyl)-21H,23H-porphyrin, 1, and its zinc(II) complex, 5,10,15-tri(4-methoxyphenyl)-20-(4-chlorophentyl)-21,23-Zinc(II)-porphine, 2, was accomplished using both conventional and "one pot" solventless microwave assisted methods with interesting comparative results. The obtained molecules were characterized by H NMR, UV-Vis and MS. These molecules are considered to represent new compounds with potential application as photosensitizers in photodynamic therapy.

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