Inorganic electrosynthesis: a green chemical method for tin complexes

Sn complexes of the series of bulky amines have been reported by electrochemical oxidation (3 h) of a tin anode in a cell containing methanol solution of the corresponding bulky amine. All were full characterized by 'H and C-NMR, IR and high resolution mass spectrometry. However, all were not e...

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Detalles Bibliográficos
Autores principales: Jiménez Pérez, Víctor Manuel, Muñoz Flores, Blanca M., Kharisov, Boris I., Hernández Fernández, Eugenio, López Cortina, Susana, Waksman de Torres, Noemí, Ramírez Durón, Rosalba
Formato: Artículo
Lenguaje:inglés
Publicado: Dra. Idalia Gómez de la Fuente 2011
Materias:
Acceso en línea:http://eprints.uanl.mx/13369/1/Art7.pdf
Descripción
Sumario:Sn complexes of the series of bulky amines have been reported by electrochemical oxidation (3 h) of a tin anode in a cell containing methanol solution of the corresponding bulky amine. All were full characterized by 'H and C-NMR, IR and high resolution mass spectrometry. However, all were not enough soluble in organic colvent in order to record its Sn-NMR spectra, this unusual behavior was attributed to the polymeric association thought intermolecular coordination OSn.