Synthesis of 3-hexylthiophene derived semiconductor polymers and composites with nanoparticles

The monomer 3-hexylthiophen-2,5-dicarboxaldehyde was synthetized from precursor 3-hexylthiophene by VilsmeierHaack reaction. Three p-type semiconductor polymers (PHT-P, PHT-B and PHT-H) were synthetized by aldol condensation from this monomer with three different ketones (propanone, butanone and hex...

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Main Authors: Vaquera, Edgar, Caballero, Arturo, Retana, Fernanda, López Cortina, Susana, Serrano, Thelma
Format: Article
Language:Spanish
Published: Universidad Autónoma de Nuevo León 2022
Subjects:
Online Access:https://quimicahoy.uanl.mx/index.php/r/article/view/306
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author Vaquera, Edgar
Caballero, Arturo
Retana, Fernanda
López Cortina, Susana
Serrano, Thelma
author_facet Vaquera, Edgar
Caballero, Arturo
Retana, Fernanda
López Cortina, Susana
Serrano, Thelma
author_sort Vaquera, Edgar
collection Artículos de Revistas UANL
description The monomer 3-hexylthiophen-2,5-dicarboxaldehyde was synthetized from precursor 3-hexylthiophene by VilsmeierHaack reaction. Three p-type semiconductor polymers (PHT-P, PHT-B and PHT-H) were synthetized by aldol condensation from this monomer with three different ketones (propanone, butanone and hexanone). Three composites were created by adding PbS/ZnS nanoparticles to these polymers. Light absorption increased to the red from polymers to composites. Electrical conductivity increased from 10% S/cm in polymers to 10! S/cm in composites.
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physical Quimica Hoy; Vol. 11 No. 04 (2022): octubre-diciembre 2022; 10-18
Quimica Hoy; Vol. 11 Núm. 04 (2022): octubre-diciembre 2022; 10-18
2007-1183
publishDate 2022
publisher Universidad Autónoma de Nuevo León
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spelling quimicahoy-article-3062023-02-14T15:03:26Z Synthesis of 3-hexylthiophene derived semiconductor polymers and composites with nanoparticles Vaquera, Edgar Caballero, Arturo Retana, Fernanda López Cortina, Susana Serrano, Thelma polymer semiconductor aldol condednsation The monomer 3-hexylthiophen-2,5-dicarboxaldehyde was synthetized from precursor 3-hexylthiophene by VilsmeierHaack reaction. Three p-type semiconductor polymers (PHT-P, PHT-B and PHT-H) were synthetized by aldol condensation from this monomer with three different ketones (propanone, butanone and hexanone). Three composites were created by adding PbS/ZnS nanoparticles to these polymers. Light absorption increased to the red from polymers to composites. Electrical conductivity increased from 10% S/cm in polymers to 10! S/cm in composites. Universidad Autónoma de Nuevo León 2022-12-13 info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion Peer review articles Articulos evaluados por pares application/pdf https://quimicahoy.uanl.mx/index.php/r/article/view/306 10.29105/qh11.04-306 Quimica Hoy; Vol. 11 No. 04 (2022): octubre-diciembre 2022; 10-18 Quimica Hoy; Vol. 11 Núm. 04 (2022): octubre-diciembre 2022; 10-18 2007-1183 spa https://quimicahoy.uanl.mx/index.php/r/article/view/306/280 https://creativecommons.org/licenses/by/4.0
spellingShingle polymer
semiconductor
aldol condednsation
Vaquera, Edgar
Caballero, Arturo
Retana, Fernanda
López Cortina, Susana
Serrano, Thelma
Synthesis of 3-hexylthiophene derived semiconductor polymers and composites with nanoparticles
thumbnail https://rediab.uanl.mx/themes/sandal5/images/article.gif
title Synthesis of 3-hexylthiophene derived semiconductor polymers and composites with nanoparticles
title_full Synthesis of 3-hexylthiophene derived semiconductor polymers and composites with nanoparticles
title_fullStr Synthesis of 3-hexylthiophene derived semiconductor polymers and composites with nanoparticles
title_full_unstemmed Synthesis of 3-hexylthiophene derived semiconductor polymers and composites with nanoparticles
title_short Synthesis of 3-hexylthiophene derived semiconductor polymers and composites with nanoparticles
title_sort synthesis of 3 hexylthiophene derived semiconductor polymers and composites with nanoparticles
topic polymer
semiconductor
aldol condednsation
topic_facet polymer
semiconductor
aldol condednsation
url https://quimicahoy.uanl.mx/index.php/r/article/view/306
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AT retanafernanda synthesisof3hexylthiophenederivedsemiconductorpolymersandcompositeswithnanoparticles
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