Gold–palladium core@shell nanoalloys: experiments and simulations
In this work, we report a facile synthesis route, structural characterization, and full atomistic simulations of gold–palladium nanoalloys. Through aberration corrected-STEM, UV-vis spectroscopy and EDS chemical analysis, we were able to determine that Au(core)–Pd(shell) bimetallic nanoparticles wer...
| Autores principales: | , , , , |
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| Formato: | Artículo |
| Lenguaje: | inglés |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | http://eprints.uanl.mx/8896/1/Gold%E2%80%93palladium%20coreshell%20nanoalloys%20experiments%20and%20simulations.pdf |
| _version_ | 1824370860989874176 |
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| author | Spitale, Ana Perez, M. A. Mejía Rosales, Sergio Yacamán, Miguel José Mariscal, Marcelo M. |
| author_facet | Spitale, Ana Perez, M. A. Mejía Rosales, Sergio Yacamán, Miguel José Mariscal, Marcelo M. |
| author_sort | Spitale, Ana |
| collection | Repositorio Institucional |
| description | In this work, we report a facile synthesis route, structural characterization, and full atomistic simulations of gold–palladium nanoalloys. Through aberration corrected-STEM, UV-vis spectroscopy and EDS chemical analysis, we were able to determine that Au(core)–Pd(shell) bimetallic nanoparticles were formed. Using different computational approaches, we were capable of establishing how the size of the core and the thickness of the shell will affect the thermodynamic stability of several core–shell nanoalloys. Finally, grand canonical simulations using different sampling procedures were used to study the growth mechanism of Pd atoms on Au seeds of different shapes. |
| format | Article |
| id | eprints-8896 |
| institution | UANL |
| language | English |
| publishDate | 2015 |
| publisher | Royal Society of Chemistry |
| record_format | eprints |
| spelling | eprints-88962016-02-22T21:14:07Z http://eprints.uanl.mx/8896/ Gold–palladium core@shell nanoalloys: experiments and simulations Spitale, Ana Perez, M. A. Mejía Rosales, Sergio Yacamán, Miguel José Mariscal, Marcelo M. Q Ciencias en General QC Física In this work, we report a facile synthesis route, structural characterization, and full atomistic simulations of gold–palladium nanoalloys. Through aberration corrected-STEM, UV-vis spectroscopy and EDS chemical analysis, we were able to determine that Au(core)–Pd(shell) bimetallic nanoparticles were formed. Using different computational approaches, we were capable of establishing how the size of the core and the thickness of the shell will affect the thermodynamic stability of several core–shell nanoalloys. Finally, grand canonical simulations using different sampling procedures were used to study the growth mechanism of Pd atoms on Au seeds of different shapes. Royal Society of Chemistry 2015 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/8896/1/Gold%E2%80%93palladium%20coreshell%20nanoalloys%20experiments%20and%20simulations.pdf http://eprints.uanl.mx/8896/1.haspreviewThumbnailVersion/Gold%E2%80%93palladium%20coreshell%20nanoalloys%20experiments%20and%20simulations.pdf Spitale, Ana y Perez, M. A. y Mejía Rosales, Sergio y Yacamán, Miguel José y Mariscal, Marcelo M. (2015) Gold–palladium core@shell nanoalloys: experiments and simulations. PCCP. Physical chemistry chemical physics, 17 (42). pp. 28060-28067. ISSN 1463-9076 |
| spellingShingle | Q Ciencias en General QC Física Spitale, Ana Perez, M. A. Mejía Rosales, Sergio Yacamán, Miguel José Mariscal, Marcelo M. Gold–palladium core@shell nanoalloys: experiments and simulations |
| thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
| title | Gold–palladium core@shell nanoalloys: experiments and simulations |
| title_full | Gold–palladium core@shell nanoalloys: experiments and simulations |
| title_fullStr | Gold–palladium core@shell nanoalloys: experiments and simulations |
| title_full_unstemmed | Gold–palladium core@shell nanoalloys: experiments and simulations |
| title_short | Gold–palladium core@shell nanoalloys: experiments and simulations |
| title_sort | gold palladium core shell nanoalloys experiments and simulations |
| topic | Q Ciencias en General QC Física |
| url | http://eprints.uanl.mx/8896/1/Gold%E2%80%93palladium%20coreshell%20nanoalloys%20experiments%20and%20simulations.pdf |
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