Solid-phase extraction of organic dyes on mixed-ligand Zr(IV) metal–organic framework

Currently, among the various areas of targeted wastewater treatment, great attention is being given by researchers to the solid-phase extraction of organic dyes using metal–organic frameworks (MOFs). In this work, a mixed-ligand Zr-MOF containing terephthalic acid and 1,10- phenanthroline as linker...

Descripción completa

Detalles Bibliográficos
Autores principales: Kharisov, Boris, Kharissova, Oxana, Zhinzhilo, Vladimir, Bryantseva, Julia, Uflyand, Igor
Formato: Artículo
Lenguaje:inglés
Publicado: Multidisciplinary Digital Publishing Institute 2022
Acceso en línea:http://eprints.uanl.mx/30174/7/30174.pdf
_version_ 1836640498855444480
author Kharisov, Boris
Kharissova, Oxana
Zhinzhilo, Vladimir
Bryantseva, Julia
Uflyand, Igor
author_facet Kharisov, Boris
Kharissova, Oxana
Zhinzhilo, Vladimir
Bryantseva, Julia
Uflyand, Igor
author_sort Kharisov, Boris
collection Repositorio Institucional
description Currently, among the various areas of targeted wastewater treatment, great attention is being given by researchers to the solid-phase extraction of organic dyes using metal–organic frameworks (MOFs). In this work, a mixed-ligand Zr-MOF containing terephthalic acid and 1,10- phenanthroline as linkers was used for this purpose. The limiting adsorption of the dyes Congo red and methylene blue, according to experimental data, is 40 mg/g. The influence of various parameters (time, temperature, adsorbent dosage, pH, and coexisting ions) on adsorption characteristics was studied. The sorbent was tested for the removal of dyes from drinks in water and in artificial seawater. The possibility of the separation of dyes by column chromatography using a sorbent as a filler was studied.
format Article
id eprints-30174
institution UANL
language English
publishDate 2022
publisher Multidisciplinary Digital Publishing Institute
record_format eprints
spelling eprints-301742025-07-01T15:33:45Z http://eprints.uanl.mx/30174/ Solid-phase extraction of organic dyes on mixed-ligand Zr(IV) metal–organic framework Kharisov, Boris Kharissova, Oxana Zhinzhilo, Vladimir Bryantseva, Julia Uflyand, Igor Currently, among the various areas of targeted wastewater treatment, great attention is being given by researchers to the solid-phase extraction of organic dyes using metal–organic frameworks (MOFs). In this work, a mixed-ligand Zr-MOF containing terephthalic acid and 1,10- phenanthroline as linkers was used for this purpose. The limiting adsorption of the dyes Congo red and methylene blue, according to experimental data, is 40 mg/g. The influence of various parameters (time, temperature, adsorbent dosage, pH, and coexisting ions) on adsorption characteristics was studied. The sorbent was tested for the removal of dyes from drinks in water and in artificial seawater. The possibility of the separation of dyes by column chromatography using a sorbent as a filler was studied. Multidisciplinary Digital Publishing Institute 2022-11-22 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/30174/7/30174.pdf http://eprints.uanl.mx/30174/7.haspreviewThumbnailVersion/30174.pdf Kharisov, Boris y Kharissova, Oxana y Zhinzhilo, Vladimir y Bryantseva, Julia y Uflyand, Igor (2022) Solid-phase extraction of organic dyes on mixed-ligand Zr(IV) metal–organic framework. Applied Sciences, 12 (23). p. 12219. ISSN 2076-3417 doi:10.3390/app122312219
spellingShingle Kharisov, Boris
Kharissova, Oxana
Zhinzhilo, Vladimir
Bryantseva, Julia
Uflyand, Igor
Solid-phase extraction of organic dyes on mixed-ligand Zr(IV) metal–organic framework
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Solid-phase extraction of organic dyes on mixed-ligand Zr(IV) metal–organic framework
title_full Solid-phase extraction of organic dyes on mixed-ligand Zr(IV) metal–organic framework
title_fullStr Solid-phase extraction of organic dyes on mixed-ligand Zr(IV) metal–organic framework
title_full_unstemmed Solid-phase extraction of organic dyes on mixed-ligand Zr(IV) metal–organic framework
title_short Solid-phase extraction of organic dyes on mixed-ligand Zr(IV) metal–organic framework
title_sort solid phase extraction of organic dyes on mixed ligand zr iv metal organic framework
url http://eprints.uanl.mx/30174/7/30174.pdf
work_keys_str_mv AT kharisovboris solidphaseextractionoforganicdyesonmixedligandzrivmetalorganicframework
AT kharissovaoxana solidphaseextractionoforganicdyesonmixedligandzrivmetalorganicframework
AT zhinzhilovladimir solidphaseextractionoforganicdyesonmixedligandzrivmetalorganicframework
AT bryantsevajulia solidphaseextractionoforganicdyesonmixedligandzrivmetalorganicframework
AT uflyandigor solidphaseextractionoforganicdyesonmixedligandzrivmetalorganicframework