Study of structural properties of BiOI on ZnO thin films and ZnO nanorods

We report the study of ZnO nanorods (ZnO-NR) decorated with BiOI nanoplatelets by the simple precipitation of BiOI in aqueous solution containing ZnO-NR powders. Likewise, as a reference for the decoration of ZnO-NR, BiOI thin films were prepared by the SILAR technique on RF magnetron-sputtered ZnO...

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Autores principales: Gutiérrez Lazos, C. D., Fundora Cruz, A., Solís Pomar, F., Pérez Tijerina, E.
Formato: Artículo
Lenguaje:inglés
Publicado: John Wiley & Sons 2019
Acceso en línea:http://eprints.uanl.mx/29820/9/29820.pdf
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author Gutiérrez Lazos, C. D.
Fundora Cruz, A.
Solís Pomar, F.
Pérez Tijerina, E.
author_facet Gutiérrez Lazos, C. D.
Fundora Cruz, A.
Solís Pomar, F.
Pérez Tijerina, E.
author_sort Gutiérrez Lazos, C. D.
collection Repositorio Institucional
description We report the study of ZnO nanorods (ZnO-NR) decorated with BiOI nanoplatelets by the simple precipitation of BiOI in aqueous solution containing ZnO-NR powders. Likewise, as a reference for the decoration of ZnO-NR, BiOI thin films were prepared by the SILAR technique on RF magnetron-sputtered ZnO thin films. The scanning electron microscopy analysis showed that BiOI grew on the ZnO-NR surfaces in nanoplatelet shape with an order of magnitude smaller in size, with respect to the platelets observed in BiOI thin films. Analysis by X-ray diffraction exhibited the hexagonal P63mc phase of ZnO and the tetragonal P4nmm crystal phase of BiOI. On the other hand, BiOI thin films are nonuniform and strongly adherent and, besides they exhibited the P4nmm tetragonal crystal structure of BiOI, they have highly preferential orientation along (001) direction (9.66°). Optical characterization of ZnO-NR/BiOI by absorbance showed a widened peak slightly shifted to infrared compared with the ZnO-NR absorbance peak, suggesting the increase of the absorption wavelength ranges from the ultraviolet to visible for ZnO-NR. Similarly, the results of the optical characterization by absorbance, for BiOI thin films, indicated the bandgap energy of the samples was between 1.78 eV and 1.88 eV, values previously reported for BiOI.
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spelling eprints-298202025-07-09T16:12:11Z http://eprints.uanl.mx/29820/ Study of structural properties of BiOI on ZnO thin films and ZnO nanorods Gutiérrez Lazos, C. D. Fundora Cruz, A. Solís Pomar, F. Pérez Tijerina, E. We report the study of ZnO nanorods (ZnO-NR) decorated with BiOI nanoplatelets by the simple precipitation of BiOI in aqueous solution containing ZnO-NR powders. Likewise, as a reference for the decoration of ZnO-NR, BiOI thin films were prepared by the SILAR technique on RF magnetron-sputtered ZnO thin films. The scanning electron microscopy analysis showed that BiOI grew on the ZnO-NR surfaces in nanoplatelet shape with an order of magnitude smaller in size, with respect to the platelets observed in BiOI thin films. Analysis by X-ray diffraction exhibited the hexagonal P63mc phase of ZnO and the tetragonal P4nmm crystal phase of BiOI. On the other hand, BiOI thin films are nonuniform and strongly adherent and, besides they exhibited the P4nmm tetragonal crystal structure of BiOI, they have highly preferential orientation along (001) direction (9.66°). Optical characterization of ZnO-NR/BiOI by absorbance showed a widened peak slightly shifted to infrared compared with the ZnO-NR absorbance peak, suggesting the increase of the absorption wavelength ranges from the ultraviolet to visible for ZnO-NR. Similarly, the results of the optical characterization by absorbance, for BiOI thin films, indicated the bandgap energy of the samples was between 1.78 eV and 1.88 eV, values previously reported for BiOI. John Wiley & Sons 2019-04-03 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/29820/9/29820.pdf http://eprints.uanl.mx/29820/9.haspreviewThumbnailVersion/29820.pdf Gutiérrez Lazos, C. D. y Fundora Cruz, A. y Solís Pomar, F. y Pérez Tijerina, E. (2019) Study of structural properties of BiOI on ZnO thin films and ZnO nanorods. Advances in Materials Science and Engineering, 2019. pp. 1-8. ISSN 1687-8434 doi:10.1155/2019/9465730
spellingShingle Gutiérrez Lazos, C. D.
Fundora Cruz, A.
Solís Pomar, F.
Pérez Tijerina, E.
Study of structural properties of BiOI on ZnO thin films and ZnO nanorods
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Study of structural properties of BiOI on ZnO thin films and ZnO nanorods
title_full Study of structural properties of BiOI on ZnO thin films and ZnO nanorods
title_fullStr Study of structural properties of BiOI on ZnO thin films and ZnO nanorods
title_full_unstemmed Study of structural properties of BiOI on ZnO thin films and ZnO nanorods
title_short Study of structural properties of BiOI on ZnO thin films and ZnO nanorods
title_sort study of structural properties of bioi on zno thin films and zno nanorods
url http://eprints.uanl.mx/29820/9/29820.pdf
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