Deposition of BiOBr thin films by thermal evaporation and evaluation of its photocatalytic activity

Thin films of BiOBr were prepared by a sequential evaporation process in a thermal evaporation system (TES) starting from BiOBr powders previously synthesized by co-precipitation. The deposition rate was fixed at 1.2A˚ s−1 to get a controlled evaporation of the material using glass slides as substr...

Descripción completa

Detalles Bibliográficos
Autores principales: López Cuéllar, Enrique Manuel, Martínez de la Cruz, Azael, Chávez Torres, N., Olivares Cortez, José Luis
Formato: Artículo
Lenguaje:Spanish / Castilian
Publicado: Elsevier 2015
Materias:
Acceso en línea:http://eprints.uanl.mx/27179/1/210.pdf
_version_ 1824420676281303040
author López Cuéllar, Enrique Manuel
Martínez de la Cruz, Azael
Chávez Torres, N.
Olivares Cortez, José Luis
author_facet López Cuéllar, Enrique Manuel
Martínez de la Cruz, Azael
Chávez Torres, N.
Olivares Cortez, José Luis
author_sort López Cuéllar, Enrique Manuel
collection Repositorio Institucional
description Thin films of BiOBr were prepared by a sequential evaporation process in a thermal evaporation system (TES) starting from BiOBr powders previously synthesized by co-precipitation. The deposition rate was fixed at 1.2A˚ s−1 to get a controlled evaporation of the material using glass slides as substrate. BiOBr thin films with a thickness of 300 nm were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The analysis by XRD of the thin film deposited confirmed the formation of BiOBr, showing a high degree of specific crystal orientation in {0 0 1} planes. In the same way, SEM analysis showed that the deposition of oxide took place by formation of plates and small particles with shape of flowers. The photocatalytic activity of BiOBr thin films was evaluated in the degradation reaction ofrhodamine B (RhB) in aqueous solution under sun-like irradiation. BiOBr thin films were able to bleach a solution of RhB (5 mg L−1) in 99% after 24 h, and to mineralize a solution of RhB (50 mg L−1) in 38% after 96 h.
format Article
id eprints-27179
institution UANL
language Spanish / Castilian
publishDate 2015
publisher Elsevier
record_format eprints
spelling eprints-271792024-12-11T16:12:51Z http://eprints.uanl.mx/27179/ Deposition of BiOBr thin films by thermal evaporation and evaluation of its photocatalytic activity López Cuéllar, Enrique Manuel Martínez de la Cruz, Azael Chávez Torres, N. Olivares Cortez, José Luis TA Ingeniería General y Civil Thin films of BiOBr were prepared by a sequential evaporation process in a thermal evaporation system (TES) starting from BiOBr powders previously synthesized by co-precipitation. The deposition rate was fixed at 1.2A˚ s−1 to get a controlled evaporation of the material using glass slides as substrate. BiOBr thin films with a thickness of 300 nm were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The analysis by XRD of the thin film deposited confirmed the formation of BiOBr, showing a high degree of specific crystal orientation in {0 0 1} planes. In the same way, SEM analysis showed that the deposition of oxide took place by formation of plates and small particles with shape of flowers. The photocatalytic activity of BiOBr thin films was evaluated in the degradation reaction ofrhodamine B (RhB) in aqueous solution under sun-like irradiation. BiOBr thin films were able to bleach a solution of RhB (5 mg L−1) in 99% after 24 h, and to mineralize a solution of RhB (50 mg L−1) in 38% after 96 h. Elsevier 2015 Article PeerReviewed text es cc_by_nc_nd http://eprints.uanl.mx/27179/1/210.pdf http://eprints.uanl.mx/27179/1.haspreviewThumbnailVersion/210.pdf López Cuéllar, Enrique Manuel y Martínez de la Cruz, Azael y Chávez Torres, N. y Olivares Cortez, José Luis (2015) Deposition of BiOBr thin films by thermal evaporation and evaluation of its photocatalytic activity. Catalysis Today, 252. pp. 2-6. ISSN 09205861 http://doi.org/10.1016/j.cattod.2015.01.013 doi:10.1016/j.cattod.2015.01.013
spellingShingle TA Ingeniería General y Civil
López Cuéllar, Enrique Manuel
Martínez de la Cruz, Azael
Chávez Torres, N.
Olivares Cortez, José Luis
Deposition of BiOBr thin films by thermal evaporation and evaluation of its photocatalytic activity
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Deposition of BiOBr thin films by thermal evaporation and evaluation of its photocatalytic activity
title_full Deposition of BiOBr thin films by thermal evaporation and evaluation of its photocatalytic activity
title_fullStr Deposition of BiOBr thin films by thermal evaporation and evaluation of its photocatalytic activity
title_full_unstemmed Deposition of BiOBr thin films by thermal evaporation and evaluation of its photocatalytic activity
title_short Deposition of BiOBr thin films by thermal evaporation and evaluation of its photocatalytic activity
title_sort deposition of biobr thin films by thermal evaporation and evaluation of its photocatalytic activity
topic TA Ingeniería General y Civil
url http://eprints.uanl.mx/27179/1/210.pdf
work_keys_str_mv AT lopezcuellarenriquemanuel depositionofbiobrthinfilmsbythermalevaporationandevaluationofitsphotocatalyticactivity
AT martinezdelacruzazael depositionofbiobrthinfilmsbythermalevaporationandevaluationofitsphotocatalyticactivity
AT chaveztorresn depositionofbiobrthinfilmsbythermalevaporationandevaluationofitsphotocatalyticactivity
AT olivarescortezjoseluis depositionofbiobrthinfilmsbythermalevaporationandevaluationofitsphotocatalyticactivity