Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions

Titanium alloys have been used in aerospace, aeronautic, automotive, biomedical, structural, and other applications because titanium alloys have less density than materials like steel and support higher stress than Al-alloys. However, components made of titanium alloys are exposed to corrosive envir...

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Autores principales: Jáquez Muñoz, Jesús Manuel, Gaona Tiburcio, Citlalli, Cabral Miramontes, José Ángel, Nieves Mendoza, Demetrio, Maldonado Bandala, Erick, Olguín Coca, Javier, López León, Luis Daimir, Flores de los Ríos, Juan Pablo, Almeraya Calderón, Facundo
Formato: Artículo
Lenguaje:inglés
Publicado: Molecular Diversity Preservation International 2021
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Acceso en línea:http://eprints.uanl.mx/25154/2/25154.pdf
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author Jáquez Muñoz, Jesús Manuel
Gaona Tiburcio, Citlalli
Cabral Miramontes, José Ángel
Nieves Mendoza, Demetrio
Maldonado Bandala, Erick
Olguín Coca, Javier
López León, Luis Daimir
Flores de los Ríos, Juan Pablo
Almeraya Calderón, Facundo
author_facet Jáquez Muñoz, Jesús Manuel
Gaona Tiburcio, Citlalli
Cabral Miramontes, José Ángel
Nieves Mendoza, Demetrio
Maldonado Bandala, Erick
Olguín Coca, Javier
López León, Luis Daimir
Flores de los Ríos, Juan Pablo
Almeraya Calderón, Facundo
author_sort Jáquez Muñoz, Jesús Manuel
collection Repositorio Institucional
description Titanium alloys have been used in aerospace, aeronautic, automotive, biomedical, structural, and other applications because titanium alloys have less density than materials like steel and support higher stress than Al-alloys. However, components made of titanium alloys are exposed to corrosive environments, the most common being industrial and marine atmospheres. This research shows the corrosion behavior of three titanium alloys, specifically Ti-CP2, Ti-6Al-2Sn-4Zr-2Mo, and Ti-6Al-4V with α, near α, and α + β alloys phases. Alloys were exposed in two electrolytes to a 3.5 wt. % H2SO4 and NaCl solution at room temperature, and their electrochemical behavior was studied by electrochemical noise technique (EN) according to ASTM ASTM-G199 standard. EN signal was filtered by three different methods, and the polynomial method was employed to obtain Rn, kurtosis, skew, and the potential spectral density analysis (PSD). The wavelets method was used, from which energy dispersion plots were obtained. The last method was Hilbert–Huang Transform (HHT), where Hilbert Spectra were analyzed. Results indicated that Rn compared with PSD showed that Ti-6Al-2Sn-4Zr-2Mo presented less dissolution in both electrolytes. Statistical methods showed that the passive layer created on Ti alloys’ surfaces is unstable; this condition is notable for Ti-6Al-2Sn-4Zr-2Mo in NaCl solution.
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spelling eprints-251542023-03-14T15:57:54Z http://eprints.uanl.mx/25154/ Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions Jáquez Muñoz, Jesús Manuel Gaona Tiburcio, Citlalli Cabral Miramontes, José Ángel Nieves Mendoza, Demetrio Maldonado Bandala, Erick Olguín Coca, Javier López León, Luis Daimir Flores de los Ríos, Juan Pablo Almeraya Calderón, Facundo Ingeniería y Tecnología TA Ingeniería General y Civil Titanium alloys have been used in aerospace, aeronautic, automotive, biomedical, structural, and other applications because titanium alloys have less density than materials like steel and support higher stress than Al-alloys. However, components made of titanium alloys are exposed to corrosive environments, the most common being industrial and marine atmospheres. This research shows the corrosion behavior of three titanium alloys, specifically Ti-CP2, Ti-6Al-2Sn-4Zr-2Mo, and Ti-6Al-4V with α, near α, and α + β alloys phases. Alloys were exposed in two electrolytes to a 3.5 wt. % H2SO4 and NaCl solution at room temperature, and their electrochemical behavior was studied by electrochemical noise technique (EN) according to ASTM ASTM-G199 standard. EN signal was filtered by three different methods, and the polynomial method was employed to obtain Rn, kurtosis, skew, and the potential spectral density analysis (PSD). The wavelets method was used, from which energy dispersion plots were obtained. The last method was Hilbert–Huang Transform (HHT), where Hilbert Spectra were analyzed. Results indicated that Rn compared with PSD showed that Ti-6Al-2Sn-4Zr-2Mo presented less dissolution in both electrolytes. Statistical methods showed that the passive layer created on Ti alloys’ surfaces is unstable; this condition is notable for Ti-6Al-2Sn-4Zr-2Mo in NaCl solution. Molecular Diversity Preservation International 2021-01-07 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/25154/2/25154.pdf http://eprints.uanl.mx/25154/2.haspreviewThumbnailVersion/25154.pdf Jáquez Muñoz, Jesús Manuel y Gaona Tiburcio, Citlalli y Cabral Miramontes, José Ángel y Nieves Mendoza, Demetrio y Maldonado Bandala, Erick y Olguín Coca, Javier y López León, Luis Daimir y Flores de los Ríos, Juan Pablo y Almeraya Calderón, Facundo (2021) Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions. Metals, 11 (1). pp. 1-23. ISSN 2075-4701 https://doi.org/10.3390/met11010105 https://doi.org/10.3390/met11010105
spellingShingle Ingeniería y Tecnología
TA Ingeniería General y Civil
Jáquez Muñoz, Jesús Manuel
Gaona Tiburcio, Citlalli
Cabral Miramontes, José Ángel
Nieves Mendoza, Demetrio
Maldonado Bandala, Erick
Olguín Coca, Javier
López León, Luis Daimir
Flores de los Ríos, Juan Pablo
Almeraya Calderón, Facundo
Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions
title_full Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions
title_fullStr Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions
title_full_unstemmed Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions
title_short Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions
title_sort electrochemical noise analysis of the corrosion of titanium alloys in nacl and h2so4 solutions
topic Ingeniería y Tecnología
TA Ingeniería General y Civil
url http://eprints.uanl.mx/25154/2/25154.pdf
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