Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions
Titanium alloys have been used in aerospace, aeronautic, automotive, biomedical, structural, and other applications because titanium alloys have less density than materials like steel and support higher stress than Al-alloys. However, components made of titanium alloys are exposed to corrosive envir...
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Formato: | Artículo |
Lenguaje: | inglés |
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Molecular Diversity Preservation International
2021
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Acceso en línea: | http://eprints.uanl.mx/25154/2/25154.pdf |
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author | Jáquez Muñoz, Jesús Manuel Gaona Tiburcio, Citlalli Cabral Miramontes, José Ángel Nieves Mendoza, Demetrio Maldonado Bandala, Erick Olguín Coca, Javier López León, Luis Daimir Flores de los Ríos, Juan Pablo Almeraya Calderón, Facundo |
author_facet | Jáquez Muñoz, Jesús Manuel Gaona Tiburcio, Citlalli Cabral Miramontes, José Ángel Nieves Mendoza, Demetrio Maldonado Bandala, Erick Olguín Coca, Javier López León, Luis Daimir Flores de los Ríos, Juan Pablo Almeraya Calderón, Facundo |
author_sort | Jáquez Muñoz, Jesús Manuel |
collection | Repositorio Institucional |
description | Titanium alloys have been used in aerospace, aeronautic, automotive, biomedical, structural, and other applications because titanium alloys have less density than materials like steel and support higher stress than Al-alloys. However, components made of titanium alloys are exposed to corrosive environments, the most common being industrial and marine atmospheres. This research shows the corrosion behavior of three titanium alloys, specifically Ti-CP2, Ti-6Al-2Sn-4Zr-2Mo, and Ti-6Al-4V with α, near α, and α + β alloys phases. Alloys were exposed in two electrolytes to a 3.5 wt. % H2SO4 and NaCl solution at room temperature, and their electrochemical behavior was studied by electrochemical noise technique (EN) according to ASTM ASTM-G199 standard. EN signal was filtered by three different methods, and the polynomial method was employed to obtain Rn, kurtosis, skew, and the potential spectral density analysis (PSD). The wavelets method was used, from which energy dispersion plots were obtained. The last method was Hilbert–Huang Transform (HHT), where Hilbert Spectra were analyzed. Results indicated that Rn compared with PSD showed that Ti-6Al-2Sn-4Zr-2Mo presented less dissolution in both electrolytes. Statistical methods showed that the passive layer created on Ti alloys’ surfaces is unstable; this condition is notable for Ti-6Al-2Sn-4Zr-2Mo in NaCl solution. |
format | Article |
id | eprints-25154 |
institution | UANL |
language | English |
publishDate | 2021 |
publisher | Molecular Diversity Preservation International |
record_format | eprints |
spelling | eprints-251542023-03-14T15:57:54Z http://eprints.uanl.mx/25154/ Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions Jáquez Muñoz, Jesús Manuel Gaona Tiburcio, Citlalli Cabral Miramontes, José Ángel Nieves Mendoza, Demetrio Maldonado Bandala, Erick Olguín Coca, Javier López León, Luis Daimir Flores de los Ríos, Juan Pablo Almeraya Calderón, Facundo Ingeniería y Tecnología TA Ingeniería General y Civil Titanium alloys have been used in aerospace, aeronautic, automotive, biomedical, structural, and other applications because titanium alloys have less density than materials like steel and support higher stress than Al-alloys. However, components made of titanium alloys are exposed to corrosive environments, the most common being industrial and marine atmospheres. This research shows the corrosion behavior of three titanium alloys, specifically Ti-CP2, Ti-6Al-2Sn-4Zr-2Mo, and Ti-6Al-4V with α, near α, and α + β alloys phases. Alloys were exposed in two electrolytes to a 3.5 wt. % H2SO4 and NaCl solution at room temperature, and their electrochemical behavior was studied by electrochemical noise technique (EN) according to ASTM ASTM-G199 standard. EN signal was filtered by three different methods, and the polynomial method was employed to obtain Rn, kurtosis, skew, and the potential spectral density analysis (PSD). The wavelets method was used, from which energy dispersion plots were obtained. The last method was Hilbert–Huang Transform (HHT), where Hilbert Spectra were analyzed. Results indicated that Rn compared with PSD showed that Ti-6Al-2Sn-4Zr-2Mo presented less dissolution in both electrolytes. Statistical methods showed that the passive layer created on Ti alloys’ surfaces is unstable; this condition is notable for Ti-6Al-2Sn-4Zr-2Mo in NaCl solution. Molecular Diversity Preservation International 2021-01-07 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/25154/2/25154.pdf http://eprints.uanl.mx/25154/2.haspreviewThumbnailVersion/25154.pdf Jáquez Muñoz, Jesús Manuel y Gaona Tiburcio, Citlalli y Cabral Miramontes, José Ángel y Nieves Mendoza, Demetrio y Maldonado Bandala, Erick y Olguín Coca, Javier y López León, Luis Daimir y Flores de los Ríos, Juan Pablo y Almeraya Calderón, Facundo (2021) Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions. Metals, 11 (1). pp. 1-23. ISSN 2075-4701 https://doi.org/10.3390/met11010105 https://doi.org/10.3390/met11010105 |
spellingShingle | Ingeniería y Tecnología TA Ingeniería General y Civil Jáquez Muñoz, Jesús Manuel Gaona Tiburcio, Citlalli Cabral Miramontes, José Ángel Nieves Mendoza, Demetrio Maldonado Bandala, Erick Olguín Coca, Javier López León, Luis Daimir Flores de los Ríos, Juan Pablo Almeraya Calderón, Facundo Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions |
thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
title | Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions |
title_full | Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions |
title_fullStr | Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions |
title_full_unstemmed | Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions |
title_short | Electrochemical Noise Analysis of the Corrosion of Titanium Alloys in NaCl and H2SO4 Solutions |
title_sort | electrochemical noise analysis of the corrosion of titanium alloys in nacl and h2so4 solutions |
topic | Ingeniería y Tecnología TA Ingeniería General y Civil |
url | http://eprints.uanl.mx/25154/2/25154.pdf |
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