Cation Xanthated Exchangers from Colombian Sub Bituminous Coals Effectively Removed Cadmium and Lead fromAqueous Solutions.

In Colombia, low rank coals are almost totally used for power and metallurgical aims, which are activities that produce contamination. In this Investigation, as an altemative to the traditional use of low rank coals, we prepared cationic xanthated exchangers from. a subbituminous coal (67.6% e, 4.6...

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Main Authors: Gómez de Arco, Lewis, Alzate Rodríguez, Liliana, Colpas Castillo, Fredy, Fernández Maestre, Roberto
Format: Article
Language:English
Published: 2011
Subjects:
Online Access:http://eprints.uanl.mx/2461/1/Art7.pdf
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author Gómez de Arco, Lewis
Alzate Rodríguez, Liliana
Colpas Castillo, Fredy
Fernández Maestre, Roberto
author_facet Gómez de Arco, Lewis
Alzate Rodríguez, Liliana
Colpas Castillo, Fredy
Fernández Maestre, Roberto
author_sort Gómez de Arco, Lewis
collection Repositorio Institucional
description In Colombia, low rank coals are almost totally used for power and metallurgical aims, which are activities that produce contamination. In this Investigation, as an altemative to the traditional use of low rank coals, we prepared cationic xanthated exchangers from. a subbituminous coal (67.6% e, 4.6% H, 22.4% O. 0.6% S, 3.2% ashes and 46.2% volatile matter) of Montelibano-Córdoba; this exchanger showed betterexchange capacities for cadmium and lead (1.8 meq/g) Iban traditional sulphonated exchangers (0.56 and 1.11 meq!g for cadmium and 1ead respectively). Xanthation was verified at 30 oc and at 5-10 oc witb NaOH and CS2. The best performance ofxanthation, determined by Infrared spectrometry and ion exchange experiments, occurred at low temperatures maybe due to CS2 volatility. By djm;njshjng tbe particle size of coa! th.e exchange capacity increased. Tbe exchange capacitywas evaIuated by flame atomic absorption spectrometry.
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spelling eprints-24612018-10-04T16:39:48Z http://eprints.uanl.mx/2461/ Cation Xanthated Exchangers from Colombian Sub Bituminous Coals Effectively Removed Cadmium and Lead fromAqueous Solutions. Gómez de Arco, Lewis Alzate Rodríguez, Liliana Colpas Castillo, Fredy Fernández Maestre, Roberto Q Ciencias en General QD Química In Colombia, low rank coals are almost totally used for power and metallurgical aims, which are activities that produce contamination. In this Investigation, as an altemative to the traditional use of low rank coals, we prepared cationic xanthated exchangers from. a subbituminous coal (67.6% e, 4.6% H, 22.4% O. 0.6% S, 3.2% ashes and 46.2% volatile matter) of Montelibano-Córdoba; this exchanger showed betterexchange capacities for cadmium and lead (1.8 meq/g) Iban traditional sulphonated exchangers (0.56 and 1.11 meq!g for cadmium and 1ead respectively). Xanthation was verified at 30 oc and at 5-10 oc witb NaOH and CS2. The best performance ofxanthation, determined by Infrared spectrometry and ion exchange experiments, occurred at low temperatures maybe due to CS2 volatility. By djm;njshjng tbe particle size of coa! th.e exchange capacity increased. Tbe exchange capacitywas evaIuated by flame atomic absorption spectrometry. 2011 Article PeerReviewed application/pdf en http://eprints.uanl.mx/2461/1/Art7.pdf http://eprints.uanl.mx/2461/1.haspreviewThumbnailVersion/Art7.pdf Gómez de Arco, Lewis y Alzate Rodríguez, Liliana y Colpas Castillo, Fredy y Fernández Maestre, Roberto (2011) Cation Xanthated Exchangers from Colombian Sub Bituminous Coals Effectively Removed Cadmium and Lead fromAqueous Solutions. Química Hoy, 2 (1).
spellingShingle Q Ciencias en General
QD Química
Gómez de Arco, Lewis
Alzate Rodríguez, Liliana
Colpas Castillo, Fredy
Fernández Maestre, Roberto
Cation Xanthated Exchangers from Colombian Sub Bituminous Coals Effectively Removed Cadmium and Lead fromAqueous Solutions.
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Cation Xanthated Exchangers from Colombian Sub Bituminous Coals Effectively Removed Cadmium and Lead fromAqueous Solutions.
title_full Cation Xanthated Exchangers from Colombian Sub Bituminous Coals Effectively Removed Cadmium and Lead fromAqueous Solutions.
title_fullStr Cation Xanthated Exchangers from Colombian Sub Bituminous Coals Effectively Removed Cadmium and Lead fromAqueous Solutions.
title_full_unstemmed Cation Xanthated Exchangers from Colombian Sub Bituminous Coals Effectively Removed Cadmium and Lead fromAqueous Solutions.
title_short Cation Xanthated Exchangers from Colombian Sub Bituminous Coals Effectively Removed Cadmium and Lead fromAqueous Solutions.
title_sort cation xanthated exchangers from colombian sub bituminous coals effectively removed cadmium and lead fromaqueous solutions
topic Q Ciencias en General
QD Química
url http://eprints.uanl.mx/2461/1/Art7.pdf
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