Doping of TiO2 Using Metal Waste (Door Key) to Improve Its Photocatalytic Efficiency in the Mineralization of an Emerging Contaminant in an Aqueous Environment

Photocatalysis is an effective advanced oxidation process to mineralize recalcitrant contaminants in aqueous media. TiO2 is the most used photocatalyst in this type of process. To improve the deficiencies of this material, one of the most used strategies has been to dope TiO2 with metallic ions. Che...

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Autores principales: Juárez Cortázar, Dany Edgar, Torres Torres, José Gilberto, Hernández Ramírez, Aracely, Arévalo Pérez, Juan Carlos, Cervantes Uribe, Adrián, Godavarthi, Srinivas, Espinosa de los Monteros, Alejandra Elvira, Silahua Pavón, Adib Abiu, Cordero García, Adrián
Formato: Artículo
Lenguaje:inglés
Publicado: Molecular Diversity Preservation International 2022
Materias:
Acceso en línea:http://eprints.uanl.mx/23516/1/23516.pdf
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author Juárez Cortázar, Dany Edgar
Torres Torres, José Gilberto
Hernández Ramírez, Aracely
Arévalo Pérez, Juan Carlos
Cervantes Uribe, Adrián
Godavarthi, Srinivas
Espinosa de los Monteros, Alejandra Elvira
Silahua Pavón, Adib Abiu
Cordero García, Adrián
author_facet Juárez Cortázar, Dany Edgar
Torres Torres, José Gilberto
Hernández Ramírez, Aracely
Arévalo Pérez, Juan Carlos
Cervantes Uribe, Adrián
Godavarthi, Srinivas
Espinosa de los Monteros, Alejandra Elvira
Silahua Pavón, Adib Abiu
Cordero García, Adrián
author_sort Juárez Cortázar, Dany Edgar
collection Repositorio Institucional
description Photocatalysis is an effective advanced oxidation process to mineralize recalcitrant contaminants in aqueous media. TiO2 is the most used photocatalyst in this type of process. To improve the deficiencies of this material, one of the most used strategies has been to dope TiO2 with metallic ions. Chemical reagents are often used as dopant precursors. However, due to the depletion of natural resources, in this work it was proposed to substitute chemical reagents and instead use a metallic residue (door key) as a doping precursor. The materials were synthesized using the sol–gel method and calcined at 400 °C to obtain the crystal structure of anatase. The characterization of the materials was carried out using X-ray diffraction (XRD), transmission electron microscopy (TEM), diffuse reflectance spectroscopy (DRS), scanning electron microscopy–energy-dispersive X-ray analysis (SEM-EDX) methods X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma optical emission spectroscopy (ICP-OES). The results obtained indicate that Cu+/Cu2+ and Zn2+ ions coexist in the support, which modifies the physicochemical properties of TiO2 and improves its photocatalytic efficiency. The synergistic effect of the dopants in TiO2 allowed the mineralization of diclofenac in an aqueous medium when T-DK (1.0) was used as photocatalyst and simulated solar radiation as an activation source.
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spelling eprints-235162024-03-06T16:00:53Z http://eprints.uanl.mx/23516/ Doping of TiO2 Using Metal Waste (Door Key) to Improve Its Photocatalytic Efficiency in the Mineralization of an Emerging Contaminant in an Aqueous Environment Juárez Cortázar, Dany Edgar Torres Torres, José Gilberto Hernández Ramírez, Aracely Arévalo Pérez, Juan Carlos Cervantes Uribe, Adrián Godavarthi, Srinivas Espinosa de los Monteros, Alejandra Elvira Silahua Pavón, Adib Abiu Cordero García, Adrián QD Química Photocatalysis is an effective advanced oxidation process to mineralize recalcitrant contaminants in aqueous media. TiO2 is the most used photocatalyst in this type of process. To improve the deficiencies of this material, one of the most used strategies has been to dope TiO2 with metallic ions. Chemical reagents are often used as dopant precursors. However, due to the depletion of natural resources, in this work it was proposed to substitute chemical reagents and instead use a metallic residue (door key) as a doping precursor. The materials were synthesized using the sol–gel method and calcined at 400 °C to obtain the crystal structure of anatase. The characterization of the materials was carried out using X-ray diffraction (XRD), transmission electron microscopy (TEM), diffuse reflectance spectroscopy (DRS), scanning electron microscopy–energy-dispersive X-ray analysis (SEM-EDX) methods X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma optical emission spectroscopy (ICP-OES). The results obtained indicate that Cu+/Cu2+ and Zn2+ ions coexist in the support, which modifies the physicochemical properties of TiO2 and improves its photocatalytic efficiency. The synergistic effect of the dopants in TiO2 allowed the mineralization of diclofenac in an aqueous medium when T-DK (1.0) was used as photocatalyst and simulated solar radiation as an activation source. Molecular Diversity Preservation International 2022 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/23516/1/23516.pdf http://eprints.uanl.mx/23516/1.haspreviewThumbnailVersion/23516.pdf Juárez Cortázar, Dany Edgar y Torres Torres, José Gilberto y Hernández Ramírez, Aracely y Arévalo Pérez, Juan Carlos y Cervantes Uribe, Adrián y Godavarthi, Srinivas y Espinosa de los Monteros, Alejandra Elvira y Silahua Pavón, Adib Abiu y Cordero García, Adrián (2022) Doping of TiO2 Using Metal Waste (Door Key) to Improve Its Photocatalytic Efficiency in the Mineralization of an Emerging Contaminant in an Aqueous Environment. Water, 14 (9). pp. 1-14. ISSN 2073-4441 http://doi.org/10.3390/w14091389 doi:10.3390/w14091389
spellingShingle QD Química
Juárez Cortázar, Dany Edgar
Torres Torres, José Gilberto
Hernández Ramírez, Aracely
Arévalo Pérez, Juan Carlos
Cervantes Uribe, Adrián
Godavarthi, Srinivas
Espinosa de los Monteros, Alejandra Elvira
Silahua Pavón, Adib Abiu
Cordero García, Adrián
Doping of TiO2 Using Metal Waste (Door Key) to Improve Its Photocatalytic Efficiency in the Mineralization of an Emerging Contaminant in an Aqueous Environment
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Doping of TiO2 Using Metal Waste (Door Key) to Improve Its Photocatalytic Efficiency in the Mineralization of an Emerging Contaminant in an Aqueous Environment
title_full Doping of TiO2 Using Metal Waste (Door Key) to Improve Its Photocatalytic Efficiency in the Mineralization of an Emerging Contaminant in an Aqueous Environment
title_fullStr Doping of TiO2 Using Metal Waste (Door Key) to Improve Its Photocatalytic Efficiency in the Mineralization of an Emerging Contaminant in an Aqueous Environment
title_full_unstemmed Doping of TiO2 Using Metal Waste (Door Key) to Improve Its Photocatalytic Efficiency in the Mineralization of an Emerging Contaminant in an Aqueous Environment
title_short Doping of TiO2 Using Metal Waste (Door Key) to Improve Its Photocatalytic Efficiency in the Mineralization of an Emerging Contaminant in an Aqueous Environment
title_sort doping of tio2 using metal waste door key to improve its photocatalytic efficiency in the mineralization of an emerging contaminant in an aqueous environment
topic QD Química
url http://eprints.uanl.mx/23516/1/23516.pdf
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