Elemental Composition and Flue Gas Emissions of Different Components from Five Semi-Arid Woody Species in Pyrolysed and Non-Pyrolysed Material

Biofuels are sustainable alternatives to fossil fuels. However, they must comply with energy efficiency requirements and contribute to environmental protection. This study was focused on elemental composition (carbon, hydrogen, nitrogen, sulphur and chlorine) of different plants’ components (stems,...

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Autores principales: Ngangyo Heya, Maginot, Foroughbakhch Pournavab, Rahim, Carrillo Parra, Artemio, Zelinski, Volker, Salas Cruz, Lidia Rosaura
Formato: Artículo
Lenguaje:inglés
Publicado: Molecular Diversity Preservation International 2019
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Acceso en línea:http://eprints.uanl.mx/23330/1/23330.pdf
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author Ngangyo Heya, Maginot
Foroughbakhch Pournavab, Rahim
Carrillo Parra, Artemio
Zelinski, Volker
Salas Cruz, Lidia Rosaura
author_facet Ngangyo Heya, Maginot
Foroughbakhch Pournavab, Rahim
Carrillo Parra, Artemio
Zelinski, Volker
Salas Cruz, Lidia Rosaura
author_sort Ngangyo Heya, Maginot
collection Repositorio Institucional
description Biofuels are sustainable alternatives to fossil fuels. However, they must comply with energy efficiency requirements and contribute to environmental protection. This study was focused on elemental composition (carbon, hydrogen, nitrogen, sulphur and chlorine) of different plants’ components (stems, branches, twigs and leaves) from pyrolysed (charcoal) and non-pyrolysed samples of five semi-arid trees: Acacia berlandieri, A. wrightii, Ebenopsis ebano, Havardia pallens and Helietta parvifolia. Carbon fluctuated from 80.77% to 89.30% in charcoal and 44.99% to 49.70% in non-pyrolysed biomass, and hydrogen ranged from 2.38% to 2.69% in charcoal and 5.89% to 6.62% in non-pyrolysed biomass. Nitrogen accounted for 0.39%⁻0.65% (branches) and 0.32%⁻0.64% (stems) in charcoal, and the ranges for non-pyrolyzed material were 2.33⁻4.00% (leaves), 1.06%⁻1.76% (twigs), 0.21%⁻0.52% (branches) and 0.15%⁻0.28% (stems). Considerably higher concentrations of sulphur compared to chlorine were found, with increasing values for both elements from the base of trees to the leaves. Non-pyrolysed samples were characterized by 68.05 mg/kg⁻769.16 mg/kg (stems), 118.02 mg/kg⁻791.68 mg/kg (branches), 225.11 mg/kg⁻1742.25 mg/kg (twigs) and 374.73 mg/kg⁻6811.52 mg/kg (leaves) for sulphur, and 117.86 mg/kg⁻528.08 mg/kg (stems), 109.18 mg/kg⁻464.15 mg/kg (branches), 905.47 mg/kg⁻4205.19 mg/kg (twigs) and 2799.68 mg/kg⁻5072.76 mg/kg (leaves) for chlorine. In charcoal, the concentration ranges for sulphur were 47.54 mg/kg⁻376.95 mg/kg (branches) and 42.73⁻292.20 mg/kg (stems) and 139.34 mg/kg⁻419.68 mg/kg (branches) and 177.39 mg/kg⁻479.16 (stems) for chlorine. The study has shown that pyrolysis increased the amount of carbon and decreased the amount of hydrogen. Coincidentally, the amount of nitrogen, chlorine and sulphur could be decreased significantly by pyrolysis which means an improvement of the fuel considering the flue gas emissions. Besides the influence of the type of combustion plant and the influence of the source of biofuel, the treatment has a significant influence on the amount and composition of flue gases emitted in the combustion.
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spelling eprints-233302022-06-01T20:22:55Z http://eprints.uanl.mx/23330/ Elemental Composition and Flue Gas Emissions of Different Components from Five Semi-Arid Woody Species in Pyrolysed and Non-Pyrolysed Material Ngangyo Heya, Maginot Foroughbakhch Pournavab, Rahim Carrillo Parra, Artemio Zelinski, Volker Salas Cruz, Lidia Rosaura TP Tecnología Química Biofuels are sustainable alternatives to fossil fuels. However, they must comply with energy efficiency requirements and contribute to environmental protection. This study was focused on elemental composition (carbon, hydrogen, nitrogen, sulphur and chlorine) of different plants’ components (stems, branches, twigs and leaves) from pyrolysed (charcoal) and non-pyrolysed samples of five semi-arid trees: Acacia berlandieri, A. wrightii, Ebenopsis ebano, Havardia pallens and Helietta parvifolia. Carbon fluctuated from 80.77% to 89.30% in charcoal and 44.99% to 49.70% in non-pyrolysed biomass, and hydrogen ranged from 2.38% to 2.69% in charcoal and 5.89% to 6.62% in non-pyrolysed biomass. Nitrogen accounted for 0.39%⁻0.65% (branches) and 0.32%⁻0.64% (stems) in charcoal, and the ranges for non-pyrolyzed material were 2.33⁻4.00% (leaves), 1.06%⁻1.76% (twigs), 0.21%⁻0.52% (branches) and 0.15%⁻0.28% (stems). Considerably higher concentrations of sulphur compared to chlorine were found, with increasing values for both elements from the base of trees to the leaves. Non-pyrolysed samples were characterized by 68.05 mg/kg⁻769.16 mg/kg (stems), 118.02 mg/kg⁻791.68 mg/kg (branches), 225.11 mg/kg⁻1742.25 mg/kg (twigs) and 374.73 mg/kg⁻6811.52 mg/kg (leaves) for sulphur, and 117.86 mg/kg⁻528.08 mg/kg (stems), 109.18 mg/kg⁻464.15 mg/kg (branches), 905.47 mg/kg⁻4205.19 mg/kg (twigs) and 2799.68 mg/kg⁻5072.76 mg/kg (leaves) for chlorine. In charcoal, the concentration ranges for sulphur were 47.54 mg/kg⁻376.95 mg/kg (branches) and 42.73⁻292.20 mg/kg (stems) and 139.34 mg/kg⁻419.68 mg/kg (branches) and 177.39 mg/kg⁻479.16 (stems) for chlorine. The study has shown that pyrolysis increased the amount of carbon and decreased the amount of hydrogen. Coincidentally, the amount of nitrogen, chlorine and sulphur could be decreased significantly by pyrolysis which means an improvement of the fuel considering the flue gas emissions. Besides the influence of the type of combustion plant and the influence of the source of biofuel, the treatment has a significant influence on the amount and composition of flue gases emitted in the combustion. Molecular Diversity Preservation International 2019 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/23330/1/23330.pdf http://eprints.uanl.mx/23330/1.haspreviewThumbnailVersion/23330.pdf Ngangyo Heya, Maginot y Foroughbakhch Pournavab, Rahim y Carrillo Parra, Artemio y Zelinski, Volker y Salas Cruz, Lidia Rosaura (2019) Elemental Composition and Flue Gas Emissions of Different Components from Five Semi-Arid Woody Species in Pyrolysed and Non-Pyrolysed Material. Sustainability, 11 (5). pp. 1-12. ISSN 2071-1050 http://doi.org/10.3390/su11051245 doi:10.3390/su11051245
spellingShingle TP Tecnología Química
Ngangyo Heya, Maginot
Foroughbakhch Pournavab, Rahim
Carrillo Parra, Artemio
Zelinski, Volker
Salas Cruz, Lidia Rosaura
Elemental Composition and Flue Gas Emissions of Different Components from Five Semi-Arid Woody Species in Pyrolysed and Non-Pyrolysed Material
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Elemental Composition and Flue Gas Emissions of Different Components from Five Semi-Arid Woody Species in Pyrolysed and Non-Pyrolysed Material
title_full Elemental Composition and Flue Gas Emissions of Different Components from Five Semi-Arid Woody Species in Pyrolysed and Non-Pyrolysed Material
title_fullStr Elemental Composition and Flue Gas Emissions of Different Components from Five Semi-Arid Woody Species in Pyrolysed and Non-Pyrolysed Material
title_full_unstemmed Elemental Composition and Flue Gas Emissions of Different Components from Five Semi-Arid Woody Species in Pyrolysed and Non-Pyrolysed Material
title_short Elemental Composition and Flue Gas Emissions of Different Components from Five Semi-Arid Woody Species in Pyrolysed and Non-Pyrolysed Material
title_sort elemental composition and flue gas emissions of different components from five semi arid woody species in pyrolysed and non pyrolysed material
topic TP Tecnología Química
url http://eprints.uanl.mx/23330/1/23330.pdf
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