2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene
The title compound, C22H20Br2N2S, was synthesized under solvent-free conditions. The molecule shows crystallographic C2 symmetry, with the S atom of the central thiophene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the molecule has a twisted con...
Autores principales: | , , , , |
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Formato: | Artículo |
Lenguaje: | inglés |
Publicado: |
Wiley-Blackwell
2014
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Materias: | |
Acceso en línea: | http://eprints.uanl.mx/23327/1/23327.pdf |
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author | Mendoza, Ángel Bernès, Sylvain Hernández Téllez, Guadalupe Portillo Moreno, Oscar Gutiérrez, René |
author_facet | Mendoza, Ángel Bernès, Sylvain Hernández Téllez, Guadalupe Portillo Moreno, Oscar Gutiérrez, René |
author_sort | Mendoza, Ángel |
collection | Repositorio Institucional |
description | The title compound, C22H20Br2N2S, was synthesized under solvent-free conditions. The molecule shows crystallographic C2 symmetry, with the S atom of the central thiophene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the molecule has a twisted conformation. The dihedral angle between the thiophene and benzene rings is 72.7 (2)° and that between the two benzene rings is 55.9 (2)°. In the crystal, molecules are arranged in a chevron-like pattern, without any significant intermolecular interactions. |
format | Article |
id | eprints-23327 |
institution | UANL |
language | English |
publishDate | 2014 |
publisher | Wiley-Blackwell |
record_format | eprints |
spelling | eprints-233272022-05-31T20:30:41Z http://eprints.uanl.mx/23327/ 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene Mendoza, Ángel Bernès, Sylvain Hernández Téllez, Guadalupe Portillo Moreno, Oscar Gutiérrez, René QD Química The title compound, C22H20Br2N2S, was synthesized under solvent-free conditions. The molecule shows crystallographic C2 symmetry, with the S atom of the central thiophene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the molecule has a twisted conformation. The dihedral angle between the thiophene and benzene rings is 72.7 (2)° and that between the two benzene rings is 55.9 (2)°. In the crystal, molecules are arranged in a chevron-like pattern, without any significant intermolecular interactions. Wiley-Blackwell 2014 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/23327/1/23327.pdf http://eprints.uanl.mx/23327/1.haspreviewThumbnailVersion/23327.pdf Mendoza, Ángel y Bernès, Sylvain y Hernández Téllez, Guadalupe y Portillo Moreno, Oscar y Gutiérrez, René (2014) 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene. Acta crystallographica. Section E, 70 (3). o345-o345. ISSN 1600-5368 http://doi.org/10.1107/S1600536814003651 doi:10.1107/S1600536814003651 |
spellingShingle | QD Química Mendoza, Ángel Bernès, Sylvain Hernández Téllez, Guadalupe Portillo Moreno, Oscar Gutiérrez, René 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene |
thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
title | 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene |
title_full | 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene |
title_fullStr | 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene |
title_full_unstemmed | 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene |
title_short | 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene |
title_sort | 2 5 bis s 1 4 bromophenyl ethyl iminomethyl thiophene |
topic | QD Química |
url | http://eprints.uanl.mx/23327/1/23327.pdf |
work_keys_str_mv | AT mendozaangel 25biss14bromophenylethyliminomethylthiophene AT bernessylvain 25biss14bromophenylethyliminomethylthiophene AT hernandeztellezguadalupe 25biss14bromophenylethyliminomethylthiophene AT portillomorenooscar 25biss14bromophenylethyliminomethylthiophene AT gutierrezrene 25biss14bromophenylethyliminomethylthiophene |