2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene

The title compound, C22H20Br2N2S, was synthesized under solvent-free conditions. The molecule shows crystallographic C2 symmetry, with the S atom of the central thiophene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the molecule has a twisted con...

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Autores principales: Mendoza, Ángel, Bernès, Sylvain, Hernández Téllez, Guadalupe, Portillo Moreno, Oscar, Gutiérrez, René
Formato: Artículo
Lenguaje:inglés
Publicado: Wiley-Blackwell 2014
Materias:
Acceso en línea:http://eprints.uanl.mx/23327/1/23327.pdf
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author Mendoza, Ángel
Bernès, Sylvain
Hernández Téllez, Guadalupe
Portillo Moreno, Oscar
Gutiérrez, René
author_facet Mendoza, Ángel
Bernès, Sylvain
Hernández Téllez, Guadalupe
Portillo Moreno, Oscar
Gutiérrez, René
author_sort Mendoza, Ángel
collection Repositorio Institucional
description The title compound, C22H20Br2N2S, was synthesized under solvent-free conditions. The molecule shows crystallographic C2 symmetry, with the S atom of the central thiophene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the molecule has a twisted conformation. The dihedral angle between the thiophene and benzene rings is 72.7 (2)° and that between the two benzene rings is 55.9 (2)°. In the crystal, molecules are arranged in a chevron-like pattern, without any significant intermolecular interactions.
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spelling eprints-233272022-05-31T20:30:41Z http://eprints.uanl.mx/23327/ 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene Mendoza, Ángel Bernès, Sylvain Hernández Téllez, Guadalupe Portillo Moreno, Oscar Gutiérrez, René QD Química The title compound, C22H20Br2N2S, was synthesized under solvent-free conditions. The molecule shows crystallographic C2 symmetry, with the S atom of the central thiophene ring lying on a twofold rotation axis. Furthermore, as a consequence of the (S,S) stereochemistry, the molecule has a twisted conformation. The dihedral angle between the thiophene and benzene rings is 72.7 (2)° and that between the two benzene rings is 55.9 (2)°. In the crystal, molecules are arranged in a chevron-like pattern, without any significant intermolecular interactions. Wiley-Blackwell 2014 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/23327/1/23327.pdf http://eprints.uanl.mx/23327/1.haspreviewThumbnailVersion/23327.pdf Mendoza, Ángel y Bernès, Sylvain y Hernández Téllez, Guadalupe y Portillo Moreno, Oscar y Gutiérrez, René (2014) 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene. Acta crystallographica. Section E, 70 (3). o345-o345. ISSN 1600-5368 http://doi.org/10.1107/S1600536814003651 doi:10.1107/S1600536814003651
spellingShingle QD Química
Mendoza, Ángel
Bernès, Sylvain
Hernández Téllez, Guadalupe
Portillo Moreno, Oscar
Gutiérrez, René
2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene
title_full 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene
title_fullStr 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene
title_full_unstemmed 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene
title_short 2,5-Bis{[(−)-(S)-1-(4-bromophenyl)ethyl]iminomethyl}thiophene
title_sort 2 5 bis s 1 4 bromophenyl ethyl iminomethyl thiophene
topic QD Química
url http://eprints.uanl.mx/23327/1/23327.pdf
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