Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins.

n this research, an extension of the kinetic and quantum yield model, as well as the evaluation of the radiation absorption phenomena on a visible-LED reactor for the photocatalytic blue wastewater degradation employing a novel polymeric material as a photocatalyst was proposed. Three novel mate...

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Autor principal: Olivo Alanís, Daniel Simón
Formato: Tesis
Lenguaje:inglés
Publicado: 2019
Materias:
Acceso en línea:http://eprints.uanl.mx/18459/1/1080289188.pdf
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author Olivo Alanís, Daniel Simón
author_facet Olivo Alanís, Daniel Simón
author_sort Olivo Alanís, Daniel Simón
collection Repositorio Institucional
description n this research, an extension of the kinetic and quantum yield model, as well as the evaluation of the radiation absorption phenomena on a visible-LED reactor for the photocatalytic blue wastewater degradation employing a novel polymeric material as a photocatalyst was proposed. Three novel materials based on phenolic resins were developed, and further characterized by electronic and optical techniques. The polymeric semiconductors were evaluated for the photocatalytic degradation of methylene blue, as well as for the synthetic blue wastewater treatment. The proposed kinetic model, for further reactor design, takes into account the generation of electron-hole pair and the reactive oxygen species via redox reactions, as well as the attack of the reactive species to the pollutant. Also, the mechanistic contribution of the different operational conditions was studied with the novel proposed effective photocatalytic mechanism model. The proposed models were validated under several operation conditions to evaluate its robustness
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spelling eprints-184592020-08-17T17:07:03Z http://eprints.uanl.mx/18459/ Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins. Olivo Alanís, Daniel Simón QD Química n this research, an extension of the kinetic and quantum yield model, as well as the evaluation of the radiation absorption phenomena on a visible-LED reactor for the photocatalytic blue wastewater degradation employing a novel polymeric material as a photocatalyst was proposed. Three novel materials based on phenolic resins were developed, and further characterized by electronic and optical techniques. The polymeric semiconductors were evaluated for the photocatalytic degradation of methylene blue, as well as for the synthetic blue wastewater treatment. The proposed kinetic model, for further reactor design, takes into account the generation of electron-hole pair and the reactive oxygen species via redox reactions, as well as the attack of the reactive species to the pollutant. Also, the mechanistic contribution of the different operational conditions was studied with the novel proposed effective photocatalytic mechanism model. The proposed models were validated under several operation conditions to evaluate its robustness 2019-05 Tesis NonPeerReviewed archive en cc_by_nc_nd http://eprints.uanl.mx/18459/1/1080289188.pdf http://eprints.uanl.mx/18459/1.haspreviewThumbnailVersion/1080289188.pdf Olivo Alanís, Daniel Simón (2019) Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins. Doctorado thesis, Universidad Autónoma de Nuevo León.
spellingShingle QD Química
Olivo Alanís, Daniel Simón
Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins.
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins.
title_full Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins.
title_fullStr Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins.
title_full_unstemmed Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins.
title_short Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins.
title_sort modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide green pigments and phenolic resins
topic QD Química
url http://eprints.uanl.mx/18459/1/1080289188.pdf
work_keys_str_mv AT olivoalanisdanielsimon modelingofthephotocatalyticreactorforbluewastewaterdegradationbyacompositebasedonzincoxidegreenpigmentsandphenolicresins