Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins.
n this research, an extension of the kinetic and quantum yield model, as well as the evaluation of the radiation absorption phenomena on a visible-LED reactor for the photocatalytic blue wastewater degradation employing a novel polymeric material as a photocatalyst was proposed. Three novel mate...
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Formato: | Tesis |
Lenguaje: | inglés |
Publicado: |
2019
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Acceso en línea: | http://eprints.uanl.mx/18459/1/1080289188.pdf |
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author | Olivo Alanís, Daniel Simón |
author_facet | Olivo Alanís, Daniel Simón |
author_sort | Olivo Alanís, Daniel Simón |
collection | Repositorio Institucional |
description | n this research, an extension of the
kinetic and quantum yield model, as well as the evaluation of the radiation
absorption phenomena on a visible-LED reactor for the photocatalytic blue
wastewater degradation employing a novel polymeric material as a photocatalyst
was proposed. Three novel materials based on phenolic resins were developed,
and further characterized by electronic and optical techniques. The polymeric
semiconductors were evaluated for the photocatalytic degradation of methylene
blue, as well as for the synthetic blue wastewater treatment. The proposed kinetic
model, for further reactor design, takes into account the generation of electron-hole
pair and the reactive oxygen species via redox reactions, as well as the attack of
the reactive species to the pollutant. Also, the mechanistic contribution of the
different operational conditions was studied with the novel proposed effective
photocatalytic mechanism model. The proposed models were validated under
several operation conditions to evaluate its robustness |
format | Tesis |
id | eprints-18459 |
institution | UANL |
language | English |
publishDate | 2019 |
record_format | eprints |
spelling | eprints-184592020-08-17T17:07:03Z http://eprints.uanl.mx/18459/ Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins. Olivo Alanís, Daniel Simón QD Química n this research, an extension of the kinetic and quantum yield model, as well as the evaluation of the radiation absorption phenomena on a visible-LED reactor for the photocatalytic blue wastewater degradation employing a novel polymeric material as a photocatalyst was proposed. Three novel materials based on phenolic resins were developed, and further characterized by electronic and optical techniques. The polymeric semiconductors were evaluated for the photocatalytic degradation of methylene blue, as well as for the synthetic blue wastewater treatment. The proposed kinetic model, for further reactor design, takes into account the generation of electron-hole pair and the reactive oxygen species via redox reactions, as well as the attack of the reactive species to the pollutant. Also, the mechanistic contribution of the different operational conditions was studied with the novel proposed effective photocatalytic mechanism model. The proposed models were validated under several operation conditions to evaluate its robustness 2019-05 Tesis NonPeerReviewed archive en cc_by_nc_nd http://eprints.uanl.mx/18459/1/1080289188.pdf http://eprints.uanl.mx/18459/1.haspreviewThumbnailVersion/1080289188.pdf Olivo Alanís, Daniel Simón (2019) Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins. Doctorado thesis, Universidad Autónoma de Nuevo León. |
spellingShingle | QD Química Olivo Alanís, Daniel Simón Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins. |
thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
title | Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins. |
title_full | Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins. |
title_fullStr | Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins. |
title_full_unstemmed | Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins. |
title_short | Modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide, green pigments, and phenolic resins. |
title_sort | modeling of the photocatalytic reactor for blue wastewater degradation by a composite based on zinc oxide green pigments and phenolic resins |
topic | QD Química |
url | http://eprints.uanl.mx/18459/1/1080289188.pdf |
work_keys_str_mv | AT olivoalanisdanielsimon modelingofthephotocatalyticreactorforbluewastewaterdegradationbyacompositebasedonzincoxidegreenpigmentsandphenolicresins |