Goethite–titania composite: disinfection mechanism under UV and visible light

Goethite–titania (a-FeOOH–TiO2) composites were prepared by co-precipitation and mechanical milling. The structural, morphological and optical properties of as-synthesized composites were characterized by X-ray powder diffraction, scanning electron microscopy and UV-Vis diffuse reflectance spectro...

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Autores principales: Lara Rico, Rosalina, Múzquiz Ramos, Elia M., López Badillo, Claudia M., García Pérez, Ulises Matías, Cruz Ortiz, Brenda R.
Formato: Artículo
Lenguaje:inglés
Publicado: 2019
Acceso en línea:http://eprints.uanl.mx/15818/1/20.pdf
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author Lara Rico, Rosalina
Múzquiz Ramos, Elia M.
López Badillo, Claudia M.
García Pérez, Ulises Matías
Cruz Ortiz, Brenda R.
author_facet Lara Rico, Rosalina
Múzquiz Ramos, Elia M.
López Badillo, Claudia M.
García Pérez, Ulises Matías
Cruz Ortiz, Brenda R.
author_sort Lara Rico, Rosalina
collection Repositorio Institucional
description Goethite–titania (a-FeOOH–TiO2) composites were prepared by co-precipitation and mechanical milling. The structural, morphological and optical properties of as-synthesized composites were characterized by X-ray powder diffraction, scanning electron microscopy and UV-Vis diffuse reflectance spectroscopy, respectively. a-FeOOH–TiO2 composites and TiO2-P25, as reference, were evaluated as photocatalysts for the disinfection of Escherichia coli under UV or visible light in a stirred tank reactor. a-FeOOH–TiO2 exhibited better photocatalytic activity in the visible region than TiO2-P25. The mechanical activation increased the absorption in the visible range of TiO2-P25 and the photocatalytic activity of a-FeOOH– TiO2. In the experiments with UV light and a-FeOOH–TiO2, mechanically activated, a 5.4 log-reduction of bacteria was achieved after 240 min of treatment. Using visible light the a-FeOOH–TiO2 and the TiO2-P25 showed a 3.1 and a 0.7 log-reductions at 240 min, respectively. The disinfection mechanism was studied by ROS detection and scavenger experiments, demonstrating that the main ROS produced in the disinfection process were superoxide radical anion, singlet oxygen and hydroxyl radical
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spelling eprints-158182019-08-13T19:45:27Z http://eprints.uanl.mx/15818/ Goethite–titania composite: disinfection mechanism under UV and visible light Lara Rico, Rosalina Múzquiz Ramos, Elia M. López Badillo, Claudia M. García Pérez, Ulises Matías Cruz Ortiz, Brenda R. Goethite–titania (a-FeOOH–TiO2) composites were prepared by co-precipitation and mechanical milling. The structural, morphological and optical properties of as-synthesized composites were characterized by X-ray powder diffraction, scanning electron microscopy and UV-Vis diffuse reflectance spectroscopy, respectively. a-FeOOH–TiO2 composites and TiO2-P25, as reference, were evaluated as photocatalysts for the disinfection of Escherichia coli under UV or visible light in a stirred tank reactor. a-FeOOH–TiO2 exhibited better photocatalytic activity in the visible region than TiO2-P25. The mechanical activation increased the absorption in the visible range of TiO2-P25 and the photocatalytic activity of a-FeOOH– TiO2. In the experiments with UV light and a-FeOOH–TiO2, mechanically activated, a 5.4 log-reduction of bacteria was achieved after 240 min of treatment. Using visible light the a-FeOOH–TiO2 and the TiO2-P25 showed a 3.1 and a 0.7 log-reductions at 240 min, respectively. The disinfection mechanism was studied by ROS detection and scavenger experiments, demonstrating that the main ROS produced in the disinfection process were superoxide radical anion, singlet oxygen and hydroxyl radical 2019-01-02 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/15818/1/20.pdf http://eprints.uanl.mx/15818/1.haspreviewThumbnailVersion/20.pdf Lara Rico, Rosalina y Múzquiz Ramos, Elia M. y López Badillo, Claudia M. y García Pérez, Ulises Matías y Cruz Ortiz, Brenda R. (2019) Goethite–titania composite: disinfection mechanism under UV and visible light. RSC Advances, 9 (5). pp. 2792-2798. ISSN 2046-2069 http://doi.org/10.1039/c8ra08412b doi:10.1039/c8ra08412b
spellingShingle Lara Rico, Rosalina
Múzquiz Ramos, Elia M.
López Badillo, Claudia M.
García Pérez, Ulises Matías
Cruz Ortiz, Brenda R.
Goethite–titania composite: disinfection mechanism under UV and visible light
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Goethite–titania composite: disinfection mechanism under UV and visible light
title_full Goethite–titania composite: disinfection mechanism under UV and visible light
title_fullStr Goethite–titania composite: disinfection mechanism under UV and visible light
title_full_unstemmed Goethite–titania composite: disinfection mechanism under UV and visible light
title_short Goethite–titania composite: disinfection mechanism under UV and visible light
title_sort goethite titania composite disinfection mechanism under uv and visible light
url http://eprints.uanl.mx/15818/1/20.pdf
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