N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate
In the title salt, C16H24N42+2NO3, both the cation and anion are placed in general positions, although the cation displays non-crystallographic inversion symmetry, with the aliphatic chain extended in an all-trans conformation. The benzene rings are almost parallel, with a dihedral angle between the...
| Autores principales: | , , , , |
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| Formato: | Artículo |
| Lenguaje: | inglés |
| Publicado: |
Wiley-Blackwell
2013
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| Materias: | |
| Acceso en línea: | http://eprints.uanl.mx/15269/1/385.pdf |
| _version_ | 1824414308779425792 |
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| author | Garza Rodríguez, Luis Ángel Elizondo Martínez, Perla Bernès, Sylvain Nájera Martínez, Blanca Pérez Rodríguez, Nancy |
| author_facet | Garza Rodríguez, Luis Ángel Elizondo Martínez, Perla Bernès, Sylvain Nájera Martínez, Blanca Pérez Rodríguez, Nancy |
| author_sort | Garza Rodríguez, Luis Ángel |
| collection | Repositorio Institucional |
| description | In the title salt, C16H24N42+2NO3, both the cation and anion are placed in general positions, although the cation displays non-crystallographic inversion symmetry, with the aliphatic chain extended in an all-trans conformation. The benzene rings are almost parallel, with a dihedral angle between their mean planes of 3.3 (6). The nitrate ions are placed in the vicinity of the protonated amine groups, forming efficient N—HO inter-ion hydrogen bonds. Each nitrate ion in the asymmetric unit bridges two symmetry-related cations, forming an R44
(18) ring, a common motif in organic ammonium
nitrate salts. This results in the formation of chains along [010] with alternating cations and anions. The neutral amine groups are involved in slightly weaker N—HO hydrogen bonds with the nitrate O atoms, and there are also a number of C—HO hydrogen bonds present. The resulting supramolecular structure is based on a two-dimensional network extending in the ab plane. |
| format | Article |
| id | eprints-15269 |
| institution | UANL |
| language | English |
| publishDate | 2013 |
| publisher | Wiley-Blackwell |
| record_format | eprints |
| spelling | eprints-152692020-03-05T22:09:43Z http://eprints.uanl.mx/15269/ N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate Garza Rodríguez, Luis Ángel Elizondo Martínez, Perla Bernès, Sylvain Nájera Martínez, Blanca Pérez Rodríguez, Nancy QD Química In the title salt, C16H24N42+2NO3, both the cation and anion are placed in general positions, although the cation displays non-crystallographic inversion symmetry, with the aliphatic chain extended in an all-trans conformation. The benzene rings are almost parallel, with a dihedral angle between their mean planes of 3.3 (6). The nitrate ions are placed in the vicinity of the protonated amine groups, forming efficient N—HO inter-ion hydrogen bonds. Each nitrate ion in the asymmetric unit bridges two symmetry-related cations, forming an R44 (18) ring, a common motif in organic ammonium nitrate salts. This results in the formation of chains along [010] with alternating cations and anions. The neutral amine groups are involved in slightly weaker N—HO hydrogen bonds with the nitrate O atoms, and there are also a number of C—HO hydrogen bonds present. The resulting supramolecular structure is based on a two-dimensional network extending in the ab plane. Wiley-Blackwell 2013 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/15269/1/385.pdf http://eprints.uanl.mx/15269/1.haspreviewThumbnailVersion/385.pdf Garza Rodríguez, Luis Ángel y Elizondo Martínez, Perla y Bernès, Sylvain y Nájera Martínez, Blanca y Pérez Rodríguez, Nancy (2013) N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate. Acta crystallographica. Section E, 69 (11). pp. 1643-1644. ISSN 1600-5368 http://doi.org/10.1107/S1600536813027475 doi:10.1107/S1600536813027475 |
| spellingShingle | QD Química Garza Rodríguez, Luis Ángel Elizondo Martínez, Perla Bernès, Sylvain Nájera Martínez, Blanca Pérez Rodríguez, Nancy N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
| thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
| title | N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
| title_full | N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
| title_fullStr | N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
| title_full_unstemmed | N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
| title_short | N,N′-Bis(2-aminobenzyl)ethane-1,2-diaminium dinitrate |
| title_sort | n n bis 2 aminobenzyl ethane 1 2 diaminium dinitrate |
| topic | QD Química |
| url | http://eprints.uanl.mx/15269/1/385.pdf |
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