Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I
The synthesis and characterization of a novel ligand, bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide (bemims), as well as a bemims-containing copper(II) coordination complex are described. In this complex, [Cu(bemims)X2] with X = NO− 3 , bemims acts as a tridentate ligand and two monodentate nitr...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
2009
|
| Online Access: | http://eprints.uanl.mx/15098/1/788.pdf |
| _version_ | 1824414258208702464 |
|---|---|
| author | Barrón Garcés, Juan D. Mendoza Díaz, Guillermo Vilchez Aguado, Florina Bernès, Sylvain |
| author_facet | Barrón Garcés, Juan D. Mendoza Díaz, Guillermo Vilchez Aguado, Florina Bernès, Sylvain |
| author_sort | Barrón Garcés, Juan D. |
| collection | Repositorio Institucional |
| description | The synthesis and characterization of a novel ligand, bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide (bemims), as well as a bemims-containing copper(II) coordination complex are described. In this complex, [Cu(bemims)X2] with X = NO− 3 , bemims acts as a tridentate ligand and two monodentate nitrate ions complete the coordination sphere. Both imidazole N atoms and the thioether S atom of bemims participate in coordination. The Cu(II) ion is five-coordinated with a slightly distorted squarepyramidal geometry (τ = .09). Electrochemical studies and spectroscopic data for this complex are compared with some blue copper proteins in order to assess its ability to mimic the copper center of type I copper proteins. |
| format | Article |
| id | eprints-15098 |
| institution | UANL |
| language | English |
| publishDate | 2009 |
| record_format | eprints |
| spelling | eprints-150982022-03-27T03:52:04Z http://eprints.uanl.mx/15098/ Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I Barrón Garcés, Juan D. Mendoza Díaz, Guillermo Vilchez Aguado, Florina Bernès, Sylvain The synthesis and characterization of a novel ligand, bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]sulfide (bemims), as well as a bemims-containing copper(II) coordination complex are described. In this complex, [Cu(bemims)X2] with X = NO− 3 , bemims acts as a tridentate ligand and two monodentate nitrate ions complete the coordination sphere. Both imidazole N atoms and the thioether S atom of bemims participate in coordination. The Cu(II) ion is five-coordinated with a slightly distorted squarepyramidal geometry (τ = .09). Electrochemical studies and spectroscopic data for this complex are compared with some blue copper proteins in order to assess its ability to mimic the copper center of type I copper proteins. 2009 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/15098/1/788.pdf http://eprints.uanl.mx/15098/1.haspreviewThumbnailVersion/788.pdf Barrón Garcés, Juan D. y Mendoza Díaz, Guillermo y Vilchez Aguado, Florina y Bernès, Sylvain (2009) Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I. Bioinorganic chemistry and applications, 2009. pp. 1-5. ISSN 1565-3633 http://doi.org/10.1155/2009/905320 doi:10.1155/2009/905320 |
| spellingShingle | Barrón Garcés, Juan D. Mendoza Díaz, Guillermo Vilchez Aguado, Florina Bernès, Sylvain Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I |
| thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
| title | Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I |
| title_full | Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I |
| title_fullStr | Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I |
| title_full_unstemmed | Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I |
| title_short | Synthesis and Characterization of bis[(2-ethyl-5-methyl-imidazo-4-yl)methyl]Sulfide and Its Coordination Behavior toward Cu(II) as a Possible Approach of a Copper Site Type I |
| title_sort | synthesis and characterization of bis 2 ethyl 5 methyl imidazo 4 yl methyl sulfide and its coordination behavior toward cu ii as a possible approach of a copper site type i |
| url | http://eprints.uanl.mx/15098/1/788.pdf |
| work_keys_str_mv | AT barrongarcesjuand synthesisandcharacterizationofbis2ethyl5methylimidazo4ylmethylsulfideanditscoordinationbehaviortowardcuiiasapossibleapproachofacoppersitetypei AT mendozadiazguillermo synthesisandcharacterizationofbis2ethyl5methylimidazo4ylmethylsulfideanditscoordinationbehaviortowardcuiiasapossibleapproachofacoppersitetypei AT vilchezaguadoflorina synthesisandcharacterizationofbis2ethyl5methylimidazo4ylmethylsulfideanditscoordinationbehaviortowardcuiiasapossibleapproachofacoppersitetypei AT bernessylvain synthesisandcharacterizationofbis2ethyl5methylimidazo4ylmethylsulfideanditscoordinationbehaviortowardcuiiasapossibleapproachofacoppersitetypei |