Unexpected reactivity of “GaI” towards N,N′-diaryl-β-diketiminate tin(II) chloride: Synthesis, X-ray diffraction analysis and DFT studies
Reaction of the [HC(CMeNAr)2]SnCl (Ar = 2,4,6-Me3C6H2) with ‘‘GaI” in THF provided an unexpected transhalogenation reaction product [HC(CMeNAr)2]SnI. The crystal structure shows a tin(II) ion with a distorted tetrahedral pyramidal geometry. Theoretical calculations, using density functional theory...
Main Authors: | Ibarra Rodríguez, Marisol, Jiménez Pérez, Víctor Manuel, Muñoz Flores, Blanca M., Waksman Minsky, Noemí Herminia, Ramírez, Rosalba, Sánchez, Mario, Hernández Ahuactzi, Iran F. |
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Format: | Article |
Language: | English |
Published: |
2015
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Online Access: | http://eprints.uanl.mx/14957/1/128.pdf |
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