Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4 − ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding.
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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2012
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| Online Access: | http://eprints.uanl.mx/14933/1/598.pdf |
| _version_ | 1824414194655559680 |
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| author | Olguín, Juan Bernès, Sylvain Gasque, Laura |
| author_facet | Olguín, Juan Bernès, Sylvain Gasque, Laura |
| author_sort | Olguín, Juan |
| collection | Repositorio Institucional |
| description | Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4 − ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding. |
| format | Article |
| id | eprints-14933 |
| institution | UANL |
| language | English |
| publishDate | 2012 |
| record_format | eprints |
| spelling | eprints-149332019-05-14T22:11:56Z http://eprints.uanl.mx/14933/ Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template Olguín, Juan Bernès, Sylvain Gasque, Laura Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4 − ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding. 2012 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/14933/1/598.pdf http://eprints.uanl.mx/14933/1.haspreviewThumbnailVersion/598.pdf Olguín, Juan y Bernès, Sylvain y Gasque, Laura (2012) Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template. Crystals, 2 (3). pp. 1357-1365. ISSN 2073-4352 http://doi.org/10.3390/cryst2031357 doi:10.3390/cryst2031357 |
| spellingShingle | Olguín, Juan Bernès, Sylvain Gasque, Laura Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
| title | Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| title_full | Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| title_fullStr | Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| title_full_unstemmed | Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| title_short | Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template |
| title_sort | fluoride ion as ligand and hydrogen bond acceptor crystal structures of two dinuclear cuii complexes built on a diazecine template |
| url | http://eprints.uanl.mx/14933/1/598.pdf |
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