Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template

Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4 − ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding.

Detalles Bibliográficos
Autores principales: Olguín, Juan, Bernès, Sylvain, Gasque, Laura
Formato: Artículo
Lenguaje:inglés
Publicado: 2012
Acceso en línea:http://eprints.uanl.mx/14933/1/598.pdf
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author Olguín, Juan
Bernès, Sylvain
Gasque, Laura
author_facet Olguín, Juan
Bernès, Sylvain
Gasque, Laura
author_sort Olguín, Juan
collection Repositorio Institucional
description Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4 − ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding.
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spelling eprints-149332019-05-14T22:11:56Z http://eprints.uanl.mx/14933/ Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template Olguín, Juan Bernès, Sylvain Gasque, Laura Two dinuclear CuII complexes based on a diazecine ligand were characterized by X-ray diffraction, one of which includes the rare CuII–F bond, resulting from dissociation of a BF4 − ion. The F− ligands actively participate in the crystal structure, behaving as acceptors for hydrogen bonding. 2012 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/14933/1/598.pdf http://eprints.uanl.mx/14933/1.haspreviewThumbnailVersion/598.pdf Olguín, Juan y Bernès, Sylvain y Gasque, Laura (2012) Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template. Crystals, 2 (3). pp. 1357-1365. ISSN 2073-4352 http://doi.org/10.3390/cryst2031357 doi:10.3390/cryst2031357
spellingShingle Olguín, Juan
Bernès, Sylvain
Gasque, Laura
Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
title_full Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
title_fullStr Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
title_full_unstemmed Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
title_short Fluoride Ion as Ligand and Hydrogen Bond Acceptor: Crystal Structures of Two Dinuclear CuII Complexes Built on a Diazecine Template
title_sort fluoride ion as ligand and hydrogen bond acceptor crystal structures of two dinuclear cuii complexes built on a diazecine template
url http://eprints.uanl.mx/14933/1/598.pdf
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