Westphalen's diol diacetate: 19(10→5)-abeo-5β-cholest-9-ene-3β,6β-diyl diacetate
The structure of the title steroid [alternative name: 3,6-diacetoxy-5-methyl-19-norcholest-9(10)-ene], C31H50O4, confirms the generally accepted mechanism for the rearrangement of a cholestan-5�-ol derivative reported a century ago by Westphalen. The methyl group at position 10 of the starting mater...
| Autores principales: | , , , , |
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| Formato: | Artículo |
| Lenguaje: | inglés |
| Publicado: |
Wiley-Blackwell
2012
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| Materias: | |
| Acceso en línea: | http://eprints.uanl.mx/14916/1/571.pdf |
| _version_ | 1824414187589206016 |
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| author | Ramírez Hernández, Johana Sandoval Ramírez, Jesús Meza Reyes, Socorro Vega Báez, José Luis Bernès, Sylvain |
| author_facet | Ramírez Hernández, Johana Sandoval Ramírez, Jesús Meza Reyes, Socorro Vega Báez, José Luis Bernès, Sylvain |
| author_sort | Ramírez Hernández, Johana |
| collection | Repositorio Institucional |
| description | The structure of the title steroid [alternative name: 3,6-diacetoxy-5-methyl-19-norcholest-9(10)-ene], C31H50O4, confirms the generally accepted mechanism for the rearrangement of a cholestan-5�-ol derivative reported a century ago by Westphalen. The methyl group at position 10 of the starting material migrates to position 5 in the steroidal nucleus, while a 9 bond is formed, as indicated by the C C bond length of
1.347 (4) A |
| format | Article |
| id | eprints-14916 |
| institution | UANL |
| language | English |
| publishDate | 2012 |
| publisher | Wiley-Blackwell |
| record_format | eprints |
| spelling | eprints-149162024-10-23T14:13:07Z http://eprints.uanl.mx/14916/ Westphalen's diol diacetate: 19(10→5)-abeo-5β-cholest-9-ene-3β,6β-diyl diacetate Ramírez Hernández, Johana Sandoval Ramírez, Jesús Meza Reyes, Socorro Vega Báez, José Luis Bernès, Sylvain QD Química The structure of the title steroid [alternative name: 3,6-diacetoxy-5-methyl-19-norcholest-9(10)-ene], C31H50O4, confirms the generally accepted mechanism for the rearrangement of a cholestan-5�-ol derivative reported a century ago by Westphalen. The methyl group at position 10 of the starting material migrates to position 5 in the steroidal nucleus, while a 9 bond is formed, as indicated by the C C bond length of 1.347 (4) A Wiley-Blackwell 2012 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/14916/1/571.pdf http://eprints.uanl.mx/14916/1.haspreviewThumbnailVersion/571.pdf Ramírez Hernández, Johana y Sandoval Ramírez, Jesús y Meza Reyes, Socorro y Vega Báez, José Luis y Bernès, Sylvain (2012) Westphalen's diol diacetate: 19(10→5)-abeo-5β-cholest-9-ene-3β,6β-diyl diacetate. Acta crystallographica. Section E, 68 (12). o3331-o3331. ISSN 1600-5368 http://doi.org/10.1107/S1600536812045278 doi:10.1107/S1600536812045278 |
| spellingShingle | QD Química Ramírez Hernández, Johana Sandoval Ramírez, Jesús Meza Reyes, Socorro Vega Báez, José Luis Bernès, Sylvain Westphalen's diol diacetate: 19(10→5)-abeo-5β-cholest-9-ene-3β,6β-diyl diacetate |
| thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
| title | Westphalen's diol diacetate: 19(10→5)-abeo-5β-cholest-9-ene-3β,6β-diyl diacetate |
| title_full | Westphalen's diol diacetate: 19(10→5)-abeo-5β-cholest-9-ene-3β,6β-diyl diacetate |
| title_fullStr | Westphalen's diol diacetate: 19(10→5)-abeo-5β-cholest-9-ene-3β,6β-diyl diacetate |
| title_full_unstemmed | Westphalen's diol diacetate: 19(10→5)-abeo-5β-cholest-9-ene-3β,6β-diyl diacetate |
| title_short | Westphalen's diol diacetate: 19(10→5)-abeo-5β-cholest-9-ene-3β,6β-diyl diacetate |
| title_sort | westphalen s diol diacetate 19 10 5 abeo 5β cholest 9 ene 3β 6β diyl diacetate |
| topic | QD Química |
| url | http://eprints.uanl.mx/14916/1/571.pdf |
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