Chemical composition, structure and properties of glass and glass-ceramic materials in the system of BaO(PbO)-B2O3-Al2O3-TiO2
The vitrification and crystallization of glasses in the system BaO(PbO)-B2O3-Al2O3-TiO2, containing (mol%): BaO (24.6-28.1), PbO (2.8-3.2), B2O3 (7.6-24.0), Al2O3 (15.9-25.5), TiO2 (39.1-41.1) were investigated. The batch compositions of different oxide molar ratios were fused in an electric furnace...
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Format: | Article |
Language: | Spanish / Castilian |
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Universidad Autónoma de Nuevo León
2011
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Online Access: | http://eprints.uanl.mx/13338/1/Art2.pdf |
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author | Ruiz Valdés, Juan Jacobo Gorokhovsky, A. Escalante García, José Iván |
author_facet | Ruiz Valdés, Juan Jacobo Gorokhovsky, A. Escalante García, José Iván |
author_sort | Ruiz Valdés, Juan Jacobo |
collection | Repositorio Institucional |
description | The vitrification and crystallization of glasses in the system BaO(PbO)-B2O3-Al2O3-TiO2, containing (mol%): BaO (24.6-28.1), PbO (2.8-3.2), B2O3 (7.6-24.0), Al2O3 (15.9-25.5), TiO2 (39.1-41.1) were investigated. The batch compositions of different oxide molar ratios were fused in an electric furnace in a platinum crucible at 1450ºC for 2h and cast into cylindrical-shaped samples. The obtained glasses were crystallized at 950ºC for 2h. BaTiO3 was recognized as a dominant crystalline phase in the produces glass-ceramic materials. The influence of B2O3 and Al2O3 contents on the chemical resistance, mechanical strength and dielectric properties was investigated. It is shown that the glass compositions containing (mol%): B2O3 7-25 and Al2O3 16-20 displayed the optimal combinations of exploitation properties. The influence of liquid phase separation on the abovementioned properties was also analyzed. |
format | Article |
id | eprints-13338 |
institution | UANL |
language | Spanish / Castilian |
publishDate | 2011 |
publisher | Universidad Autónoma de Nuevo León |
record_format | eprints |
spelling | eprints-133382018-01-31T20:01:16Z http://eprints.uanl.mx/13338/ Chemical composition, structure and properties of glass and glass-ceramic materials in the system of BaO(PbO)-B2O3-Al2O3-TiO2 Ruiz Valdés, Juan Jacobo Gorokhovsky, A. Escalante García, José Iván QD Química The vitrification and crystallization of glasses in the system BaO(PbO)-B2O3-Al2O3-TiO2, containing (mol%): BaO (24.6-28.1), PbO (2.8-3.2), B2O3 (7.6-24.0), Al2O3 (15.9-25.5), TiO2 (39.1-41.1) were investigated. The batch compositions of different oxide molar ratios were fused in an electric furnace in a platinum crucible at 1450ºC for 2h and cast into cylindrical-shaped samples. The obtained glasses were crystallized at 950ºC for 2h. BaTiO3 was recognized as a dominant crystalline phase in the produces glass-ceramic materials. The influence of B2O3 and Al2O3 contents on the chemical resistance, mechanical strength and dielectric properties was investigated. It is shown that the glass compositions containing (mol%): B2O3 7-25 and Al2O3 16-20 displayed the optimal combinations of exploitation properties. The influence of liquid phase separation on the abovementioned properties was also analyzed. Universidad Autónoma de Nuevo León 2011-03-10 Article PeerReviewed text es cc_by_nc_nd http://eprints.uanl.mx/13338/1/Art2.pdf http://eprints.uanl.mx/13338/1.haspreviewThumbnailVersion/Art2.pdf Ruiz Valdés, Juan Jacobo y Gorokhovsky, A. y Escalante García, José Iván (2011) Chemical composition, structure and properties of glass and glass-ceramic materials in the system of BaO(PbO)-B2O3-Al2O3-TiO2. Química Hoy, 1 (2). pp. 10-12. ISSN 2007-1183 |
spellingShingle | QD Química Ruiz Valdés, Juan Jacobo Gorokhovsky, A. Escalante García, José Iván Chemical composition, structure and properties of glass and glass-ceramic materials in the system of BaO(PbO)-B2O3-Al2O3-TiO2 |
thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
title | Chemical composition, structure and properties of glass and glass-ceramic materials in the system of BaO(PbO)-B2O3-Al2O3-TiO2 |
title_full | Chemical composition, structure and properties of glass and glass-ceramic materials in the system of BaO(PbO)-B2O3-Al2O3-TiO2 |
title_fullStr | Chemical composition, structure and properties of glass and glass-ceramic materials in the system of BaO(PbO)-B2O3-Al2O3-TiO2 |
title_full_unstemmed | Chemical composition, structure and properties of glass and glass-ceramic materials in the system of BaO(PbO)-B2O3-Al2O3-TiO2 |
title_short | Chemical composition, structure and properties of glass and glass-ceramic materials in the system of BaO(PbO)-B2O3-Al2O3-TiO2 |
title_sort | chemical composition structure and properties of glass and glass ceramic materials in the system of bao pbo b2o3 al2o3 tio2 |
topic | QD Química |
url | http://eprints.uanl.mx/13338/1/Art2.pdf |
work_keys_str_mv | AT ruizvaldesjuanjacobo chemicalcompositionstructureandpropertiesofglassandglassceramicmaterialsinthesystemofbaopbob2o3al2o3tio2 AT gorokhovskya chemicalcompositionstructureandpropertiesofglassandglassceramicmaterialsinthesystemofbaopbob2o3al2o3tio2 AT escalantegarciajoseivan chemicalcompositionstructureandpropertiesofglassandglassceramicmaterialsinthesystemofbaopbob2o3al2o3tio2 |