Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol

The asymmetric unit of the title compound C17H16N4O5, contains one molecule of the compound (L3)(1,3-bis(2-nitrobenzylideneamino)propan-2-ol). The molecule shows a chiral C atom but the absolute structure was not possible to be determined by X-ray diffraction. The molecule shows intermolecular hydro...

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Main Authors: Elizondo Martínez, Perla, Pérez Rodríguez, Nancy, Rodríguez de Barbarín, Cecilia, López Cortina, Susana, Rodríguez de Luna, Sara Luisa
Format: Article
Language:English
Published: Universidad Autónoma de Nuevo León 2010
Subjects:
Online Access:http://eprints.uanl.mx/13330/1/Art2.pdf
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author Elizondo Martínez, Perla
Pérez Rodríguez, Nancy
Rodríguez de Barbarín, Cecilia
López Cortina, Susana
Rodríguez de Luna, Sara Luisa
author_facet Elizondo Martínez, Perla
Pérez Rodríguez, Nancy
Rodríguez de Barbarín, Cecilia
López Cortina, Susana
Rodríguez de Luna, Sara Luisa
author_sort Elizondo Martínez, Perla
collection Repositorio Institucional
description The asymmetric unit of the title compound C17H16N4O5, contains one molecule of the compound (L3)(1,3-bis(2-nitrobenzylideneamino)propan-2-ol). The molecule shows a chiral C atom but the absolute structure was not possible to be determined by X-ray diffraction. The molecule shows intermolecular hydrogen bonding involving the hydroxy group and an imine nitrogen atom of a symmetry related molecule. The molecular distribution shows weak interactions between oxygen atoms of the nitro groups and two different C-H groups of benzene rings. The extended weak H bond formation, using the NO2 groups, probably gives a more stable crystal structure. The molecule represents a precursor of a polyaza macrocyclic ligands.
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spelling eprints-133302019-06-25T08:25:22Z http://eprints.uanl.mx/13330/ Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol Elizondo Martínez, Perla Pérez Rodríguez, Nancy Rodríguez de Barbarín, Cecilia López Cortina, Susana Rodríguez de Luna, Sara Luisa QD Química The asymmetric unit of the title compound C17H16N4O5, contains one molecule of the compound (L3)(1,3-bis(2-nitrobenzylideneamino)propan-2-ol). The molecule shows a chiral C atom but the absolute structure was not possible to be determined by X-ray diffraction. The molecule shows intermolecular hydrogen bonding involving the hydroxy group and an imine nitrogen atom of a symmetry related molecule. The molecular distribution shows weak interactions between oxygen atoms of the nitro groups and two different C-H groups of benzene rings. The extended weak H bond formation, using the NO2 groups, probably gives a more stable crystal structure. The molecule represents a precursor of a polyaza macrocyclic ligands. Universidad Autónoma de Nuevo León 2010-12-10 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/13330/1/Art2.pdf http://eprints.uanl.mx/13330/1.haspreviewThumbnailVersion/Art2.pdf Elizondo Martínez, Perla y Pérez Rodríguez, Nancy y Rodríguez de Barbarín, Cecilia y López Cortina, Susana y Rodríguez de Luna, Sara Luisa (2010) Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol. Química Hoy, 1 (1). pp. 6-9. ISSN 2007-1183
spellingShingle QD Química
Elizondo Martínez, Perla
Pérez Rodríguez, Nancy
Rodríguez de Barbarín, Cecilia
López Cortina, Susana
Rodríguez de Luna, Sara Luisa
Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol
thumbnail https://rediab.uanl.mx/themes/sandal5/images/online.png
title Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol
title_full Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol
title_fullStr Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol
title_full_unstemmed Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol
title_short Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol
title_sort synthesis and crystal structures of a poliaza receptor macroligand 1 3 bis 2 nitrobenzylideneamino propan 2 ol
topic QD Química
url http://eprints.uanl.mx/13330/1/Art2.pdf
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