Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol
The asymmetric unit of the title compound C17H16N4O5, contains one molecule of the compound (L3)(1,3-bis(2-nitrobenzylideneamino)propan-2-ol). The molecule shows a chiral C atom but the absolute structure was not possible to be determined by X-ray diffraction. The molecule shows intermolecular hydro...
| Autores principales: | , , , , |
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| Formato: | Artículo |
| Lenguaje: | inglés |
| Publicado: |
Universidad Autónoma de Nuevo León
2010
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| Materias: | |
| Acceso en línea: | http://eprints.uanl.mx/13330/1/Art2.pdf |
| _version_ | 1824413684327251968 |
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| author | Elizondo Martínez, Perla Pérez Rodríguez, Nancy Rodríguez de Barbarín, Cecilia López Cortina, Susana Rodríguez de Luna, Sara Luisa |
| author_facet | Elizondo Martínez, Perla Pérez Rodríguez, Nancy Rodríguez de Barbarín, Cecilia López Cortina, Susana Rodríguez de Luna, Sara Luisa |
| author_sort | Elizondo Martínez, Perla |
| collection | Repositorio Institucional |
| description | The asymmetric unit of the title compound C17H16N4O5, contains one molecule of the compound (L3)(1,3-bis(2-nitrobenzylideneamino)propan-2-ol). The molecule shows a chiral C atom but the absolute structure was not possible to be determined by X-ray diffraction. The molecule shows intermolecular hydrogen bonding involving the hydroxy group and an imine nitrogen atom of a symmetry related molecule. The molecular distribution shows weak interactions between oxygen atoms of the nitro groups and two different C-H groups of benzene rings. The extended weak H bond formation, using the NO2 groups, probably gives a more stable crystal structure. The molecule represents a precursor of a polyaza macrocyclic ligands. |
| format | Article |
| id | eprints-13330 |
| institution | UANL |
| language | English |
| publishDate | 2010 |
| publisher | Universidad Autónoma de Nuevo León |
| record_format | eprints |
| spelling | eprints-133302019-06-25T08:25:22Z http://eprints.uanl.mx/13330/ Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol Elizondo Martínez, Perla Pérez Rodríguez, Nancy Rodríguez de Barbarín, Cecilia López Cortina, Susana Rodríguez de Luna, Sara Luisa QD Química The asymmetric unit of the title compound C17H16N4O5, contains one molecule of the compound (L3)(1,3-bis(2-nitrobenzylideneamino)propan-2-ol). The molecule shows a chiral C atom but the absolute structure was not possible to be determined by X-ray diffraction. The molecule shows intermolecular hydrogen bonding involving the hydroxy group and an imine nitrogen atom of a symmetry related molecule. The molecular distribution shows weak interactions between oxygen atoms of the nitro groups and two different C-H groups of benzene rings. The extended weak H bond formation, using the NO2 groups, probably gives a more stable crystal structure. The molecule represents a precursor of a polyaza macrocyclic ligands. Universidad Autónoma de Nuevo León 2010-12-10 Article PeerReviewed text en cc_by_nc_nd http://eprints.uanl.mx/13330/1/Art2.pdf http://eprints.uanl.mx/13330/1.haspreviewThumbnailVersion/Art2.pdf Elizondo Martínez, Perla y Pérez Rodríguez, Nancy y Rodríguez de Barbarín, Cecilia y López Cortina, Susana y Rodríguez de Luna, Sara Luisa (2010) Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol. Química Hoy, 1 (1). pp. 6-9. ISSN 2007-1183 |
| spellingShingle | QD Química Elizondo Martínez, Perla Pérez Rodríguez, Nancy Rodríguez de Barbarín, Cecilia López Cortina, Susana Rodríguez de Luna, Sara Luisa Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol |
| thumbnail | https://rediab.uanl.mx/themes/sandal5/images/online.png |
| title | Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol |
| title_full | Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol |
| title_fullStr | Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol |
| title_full_unstemmed | Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol |
| title_short | Synthesis and crystal structures of a poliaza receptor macroligand: 1,3-bis(2-nitrobenzylideneamino)propan-2-ol |
| title_sort | synthesis and crystal structures of a poliaza receptor macroligand 1 3 bis 2 nitrobenzylideneamino propan 2 ol |
| topic | QD Química |
| url | http://eprints.uanl.mx/13330/1/Art2.pdf |
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