Effect of rare earth dopants on structural and mechanical properties of nanoceria synthesized by combustion method

Structural characteristics of combustion synthesized, calcined and densified pure and doped nanoceria with tri-valent cations of Er, Y, Gd, Sm and Nd were analyzed by X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). The results showed that the as-synthesized and...

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Bibliographic Details
Main Authors: Akbari Fakhrabadi, Ali, Meruane, V., Jamshidijam, M., Gracia Pinilla, Miguel Ángel, Mangalaraja, Ramalinga Viswanathan
Format: Article
Language:English
Published: 2015
Subjects:
Online Access:http://eprints.uanl.mx/11598/1/1-s2.0-S0921509315304639-main.pdf
Description
Summary:Structural characteristics of combustion synthesized, calcined and densified pure and doped nanoceria with tri-valent cations of Er, Y, Gd, Sm and Nd were analyzed by X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). The results showed that the as-synthesized and calcined nanopowders were mesoporous and calculated lattice parameters were close to theoretical ion-packing model. The effect of dopants on elastic modulus, microhardness and fracture toughness of sintered pure and doped ceria were investigated. It was observed that tri-valent cation dopants increased the hardness of the ceria, whereas the fracture toughness and elastic modulus were decreased.